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Abstract:

Mesoporous crystalline (hydr)oxides of low-valence metal ions (M(II) and M(III)) are highly demanded in the context of various applications. In this study, we demonstrate key factors to the successful formation of ordered mesoporous films through the assembly of nanobuilding block (ANBB) approach using a colloidal solution of crystalline M(OH) 2 (M = Mn, Fe, Co, Ni, and Cu). The colloidal system of α-Ni(OH) 2 is presented in depth as a typical example. Crystal growth and aggregation kinetics of the NBB were tuned by synthetic parameters. Nanometer-sized NBBs of tailored size between oligomer scale to over 20 nm were obtained. The films prepared from α-Ni(OH) 2 NBBs with a diameter of ≤7.5 nm showed ordered mesostructures through evaporation-induced self-assembly in the presence of supramolecular templates. Coarse-grained simulations suggest that there is a threshold diameter of NBB toward the formation of well-ordered mesostructures. It was found that, as well as limiting the diameter of NBB, inhibition of an aggregation of NBBs by using coordinative additives or diluting the NBB colloidal solution was essential to control the assembly of NBBs and templates into the ordered mesostructures. The results obtained here open up the synthesis of ordered mesoporous materials with a crystalline wall of variety of chemical compositions containing low-valence metal elements. © 2018 American Chemical Society.

Registro:

Documento: Artículo
Título:Highly Ordered Mesoporous Hydroxide Thin Films through Self-Assembly of Size-Tailored Nanobuilding Blocks: A Theoretical-Experimental Approach
Autor:Tarutani, N.; Tokudome, Y.; Jobbágy, M.; Soler-Illia, G.J.A.A.; Tang, Q.; Müller, M.; Takahashi, M.
Filiación:Department of Materials Science, Graduate School of Engineering, Osaka Prefecture University, Sakai, Osaka, 599-8531, Japan
INQUIMAE-CONICET, Facultad Ciencias Exactas y Naturales, Universidad de Buenos Aires, Buenos Aires, C1428EHA, Argentina
Instituto de Nanosistemas, Universidad Nacional de General San Martín-CONICET, Av. 25 de Mayo y Francia, San Martín, 1650, Argentina
Institut für Theoretische Physik, Universität Göttingen, Friedrich-Hund-Platz 1, Göttingen, 37077, Germany
Department of Chemical Science and Technology, Faculty of Bioscience and Applied Chemistry, Hosei University, Koganei, Tokyo, 184-8584, Japan
Palabras clave:Additives; Agglomeration; Chromium compounds; Crystalline materials; Growth kinetics; Metal ions; Metals; Self assembly; Sols; Thin films; Aggregation kinetics; Chemical compositions; Evaporation induced self assemblies; Experimental approaches; Hydroxide thin films; Ordered mesoporous materials; Supramolecular templates; Synthetic parameters; Mesoporous materials
Año:2019
Volumen:31
Número:2
Página de inicio:322
Página de fin:330
DOI: http://dx.doi.org/10.1021/acs.chemmater.8b03082
Título revista:Chemistry of Materials
Título revista abreviado:Chem. Mater.
ISSN:08974756
CODEN:CMATE
Registro:https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_08974756_v31_n2_p322_Tarutani

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Citas:

---------- APA ----------
Tarutani, N., Tokudome, Y., Jobbágy, M., Soler-Illia, G.J.A.A., Tang, Q., Müller, M. & Takahashi, M. (2019) . Highly Ordered Mesoporous Hydroxide Thin Films through Self-Assembly of Size-Tailored Nanobuilding Blocks: A Theoretical-Experimental Approach. Chemistry of Materials, 31(2), 322-330.
http://dx.doi.org/10.1021/acs.chemmater.8b03082
---------- CHICAGO ----------
Tarutani, N., Tokudome, Y., Jobbágy, M., Soler-Illia, G.J.A.A., Tang, Q., Müller, M., et al. "Highly Ordered Mesoporous Hydroxide Thin Films through Self-Assembly of Size-Tailored Nanobuilding Blocks: A Theoretical-Experimental Approach" . Chemistry of Materials 31, no. 2 (2019) : 322-330.
http://dx.doi.org/10.1021/acs.chemmater.8b03082
---------- MLA ----------
Tarutani, N., Tokudome, Y., Jobbágy, M., Soler-Illia, G.J.A.A., Tang, Q., Müller, M., et al. "Highly Ordered Mesoporous Hydroxide Thin Films through Self-Assembly of Size-Tailored Nanobuilding Blocks: A Theoretical-Experimental Approach" . Chemistry of Materials, vol. 31, no. 2, 2019, pp. 322-330.
http://dx.doi.org/10.1021/acs.chemmater.8b03082
---------- VANCOUVER ----------
Tarutani, N., Tokudome, Y., Jobbágy, M., Soler-Illia, G.J.A.A., Tang, Q., Müller, M., et al. Highly Ordered Mesoporous Hydroxide Thin Films through Self-Assembly of Size-Tailored Nanobuilding Blocks: A Theoretical-Experimental Approach. Chem. Mater. 2019;31(2):322-330.
http://dx.doi.org/10.1021/acs.chemmater.8b03082