Abstract:
We present an atomization system for atomic absorption spectrometry comprised of a stainless steel furnace heated by the Joule effect by means of its intrinsic resistance. This new kind of furnace does not require any gases during operation. Samples are introduced with an independently controlled thermospray injector. The device outperforms conventional FAAS (Flame Atomic Absorption Spectrometry) for many analytes, providing a very safe, compact and inexpensive alternative for many analytical determinations. Full characterization of the system is presented, and theoretical simulations are contrasted with experimental data. © 2017 The Royal Society of Chemistry.
Registro:
Documento: |
Artículo
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Título: | Electrothermal metallic furnace atomic absorption spectrometry |
Autor: | Morzan, E.; Carrone, G.; Tudino, M.; Etchenique, R. |
Filiación: | Departamento de Química Inorgánica, Analítica y Química Física, INQUIMAE, Facultad de Ciencias Exactas y Naturales, Universidad de Buenos Aires, Ciudad Universitaria, Pabellón 2, Buenos Aires, AR1428EHA, Argentina
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Palabras clave: | Absorption spectroscopy; Atoms; Furnaces; Spectrometry; Stainless steel; Analytes; Analytical determination; Flame atomic absorption spectrometry; Intrinsic resistance; Joule effects; Theoretical simulation; Thermospray; Atomic absorption spectrometry |
Año: | 2017
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Volumen: | 9
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Número: | 5
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Página de inicio: | 756
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Página de fin: | 760
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DOI: |
http://dx.doi.org/10.1039/c6ay03331h |
Título revista: | Analytical Methods
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Título revista abreviado: | Anal. Methods
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ISSN: | 17599660
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Registro: | https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_17599660_v9_n5_p756_Morzan |
Referencias:
- Walsh, A., (1955) Spectrochim. Acta, 7, pp. 108-117
- Butcher, D.J., (2013) Appl. Spectrosc. Rev., 48 (4), pp. 261-328
- Bings, N.H., Bogaerts, A., Broekaert, J.A.C., (2013) Anal. Chem., 85 (2), pp. 670-704
- Hill, S., Dawson, J., Price, W., Shuttler, L., Smith, C.M., Tyson, J.F., (1997) J. Anal. At. Spectrom., 12 (8), pp. 327-379
- West, T.S., Williams, K.K., (1965) Anal. Chim. Acta, 45 (1), pp. 25-41
- Ĺvov, B.V., (1988) J. Anal. At. Spectrom., 3 (1), pp. 9-12
- Ĺvov, B.V., (1997) Spectrochim. Acta, Part B, 52 (910), pp. 1239-1245
- Maia, S.M., Ganzarolli, B.E., Curtius, A., (2002) Spectrochim. Acta, Part B, 57 (3), pp. 473-484
- Ĺvov, B.V., (1969) Spectrochim. Acta, Part B, 24 (1), pp. 53-56
- Sturgeon, R., (1996) Fresenius' J. Anal. Chem., 355 (56), pp. 425-432
- Hieftje, G., (1990) Fresenius' J. Anal. Chem., 337 (5), pp. 528-537
- Holcombe, J.A., Borges, D.L., Graphite Furnace Atomic Absorption Spectrometry (2010) Encyclopedia of Analytical Chemistry
- Czobik, E.J., Matousek, J.P., (1980) Spectrochim. Acta, Part B, 35 (1112), pp. 741-751
- Muzgin, V.N., Atnashev, Y.B., Korepanov, V.E., Pupyshev, A.A., (1987) Talanta, 34 (1), pp. 197-200
- Berndt, H., Schaidach, G., (1988) J. Anal. At. Spectrom., 3 (5), pp. 709-712
- Williams, M., Piepmeir, E., (1972) Anal. Chem., 44 (7), pp. 1342-1344
- Sperling, M., Welz, B., Hertzberg, J., Rieck, C., Marowsky, G., (2006) Spectrochim. Acta, Part B, 51 (910), pp. 897-930
- Frech, W., Ĺvov, B., (1993) Spectrochim. Acta, Part B, 48 (11), pp. 1371-1379
- Gáspár, A., Berndt, H., (2000) Anal. Chem., 72, pp. 240-246
- Brancalion, M.L., Sabadini, E., Arruda, M.A.Z., (2007) Anal. Chem., 79, pp. 6527-6533
- Wu, P., Zhang, Y., Liu, R., Lv, Y., Hou, X., (2009) Talanta, 77, pp. 1778-1782
- Brancalion, M.L., Sabadini, E., Arruda, M.A.Z., (2009) Spectrochim. Acta, Part B, 64, pp. 89-94
- Morzan, E., Piano, O., Stripeikis, J., Tudino, M., (2012) Spectrochim. Acta, Part B, 77, pp. 58-62
- Musil, S., Dědina, J., (2013) J. Anal. At. Spectrom., 28, pp. 593-600
- Morzan, E., Stripeikis, J., Goicoechea, H., Tudino, M., (2016) Chemom. Intell. Lab. Syst., 151, pp. 44-50
- Schneider, C.A., Rasband, W.S., Eliceiri, K.W., (2012) Nat. Methods, 9 (7), pp. 671-675
- Standard Specification for Seamless, Welded, and Heavily Cold Worked Austenitic Stainless Steel Pipes, , ASTM A312/A312M
Citas:
---------- APA ----------
Morzan, E., Carrone, G., Tudino, M. & Etchenique, R.
(2017)
. Electrothermal metallic furnace atomic absorption spectrometry. Analytical Methods, 9(5), 756-760.
http://dx.doi.org/10.1039/c6ay03331h---------- CHICAGO ----------
Morzan, E., Carrone, G., Tudino, M., Etchenique, R.
"Electrothermal metallic furnace atomic absorption spectrometry"
. Analytical Methods 9, no. 5
(2017) : 756-760.
http://dx.doi.org/10.1039/c6ay03331h---------- MLA ----------
Morzan, E., Carrone, G., Tudino, M., Etchenique, R.
"Electrothermal metallic furnace atomic absorption spectrometry"
. Analytical Methods, vol. 9, no. 5, 2017, pp. 756-760.
http://dx.doi.org/10.1039/c6ay03331h---------- VANCOUVER ----------
Morzan, E., Carrone, G., Tudino, M., Etchenique, R. Electrothermal metallic furnace atomic absorption spectrometry. Anal. Methods. 2017;9(5):756-760.
http://dx.doi.org/10.1039/c6ay03331h