Artículo

Viva, F.; Heredia, N.; Palmbaum, S.P.; Diaz, L.; De Diego, J.; Lozano, M.; Bruno, M.; Corti, H. "Spray-casting ABPBI membranes for high temperature PEM fuel cells" (2017) Journal of the Electrochemical Society. 164(7):F866-F872
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Abstract:

The preparation and characterization of membranes of poly[2,5-benzimidazole] (ABPBI) by spray casting at room temperature from an ethanol solution is described. The prepared membranes doped with 11 M H3PO4 sorbed 1.5 molecules of acid per imidazole ring exhibiting a proton conductivity of 0.05 S · cm−1 at 153◦C. The 80 μm thick, homogeneous, membranes obtained were used for the preparation of a membrane electrode assembly (MEA). Fuel cell test conducted with the prepared MEA at temperatures between 100 and 180◦C shows an increase in the performance with temperature, with a maximum power density of 200 mW · cm−2 at 180◦C. The described ABPBI membrane preparation method from an ethanol solution at low temperature opens a simple route for overcoming the processability problems of the aforementioned polymer. © 2017 The Electrochemical Society. All rights reserved.

Registro:

Documento: Artículo
Título:Spray-casting ABPBI membranes for high temperature PEM fuel cells
Autor:Viva, F.; Heredia, N.; Palmbaum, S.P.; Diaz, L.; De Diego, J.; Lozano, M.; Bruno, M.; Corti, H.
Filiación:Departamento de Física de la Materia Condensada, Gerencia de Investigaciones y Aplicaciones, Comisión Nacional de Energía Atómica (CNEA), Av. Gral. Paz 1499, Buenos Aires, B1650KNA, Argentina
Centro de Procesos Superficiales, Instituto Nacional de Tecnología Industrial (INTI), Av. Gral. Paz 5445B1650KNA, Argentina
Escuela de Ciencia y Tecnología, Universidad de Gral, Martín de Irigoyen 3100, San Martín, B1650KNA, Argentina
Instituto de Química Física de los Materiales, Medio Ambiente y Energía (INQUIMAE), Universidad de Buenos Aires, Pabellón II, Ciudad Universitaria1428, Argentina
Palabras clave:Ethanol; Ethanolamines; Fuel cells; Membranes; Ethanol solutions; Fuel cell tests; High temperature pem fuel cells; Low temperatures; Maximum power density; Membrane electrode assemblies; Membrane preparation; Processability; Proton exchange membrane fuel cells (PEMFC)
Año:2017
Volumen:164
Número:7
Página de inicio:F866
Página de fin:F872
DOI: http://dx.doi.org/10.1149/2.1621707jes
Título revista:Journal of the Electrochemical Society
Título revista abreviado:J Electrochem Soc
ISSN:00134651
CODEN:JESOA
Registro:http://digital.bl.fcen.uba.ar/collection/paper/document/paper_00134651_v164_n7_pF866_Viva

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Citas:

---------- APA ----------
Viva, F., Heredia, N., Palmbaum, S.P., Diaz, L., De Diego, J., Lozano, M., Bruno, M.,..., Corti, H. (2017) . Spray-casting ABPBI membranes for high temperature PEM fuel cells. Journal of the Electrochemical Society, 164(7), F866-F872.
http://dx.doi.org/10.1149/2.1621707jes
---------- CHICAGO ----------
Viva, F., Heredia, N., Palmbaum, S.P., Diaz, L., De Diego, J., Lozano, M., et al. "Spray-casting ABPBI membranes for high temperature PEM fuel cells" . Journal of the Electrochemical Society 164, no. 7 (2017) : F866-F872.
http://dx.doi.org/10.1149/2.1621707jes
---------- MLA ----------
Viva, F., Heredia, N., Palmbaum, S.P., Diaz, L., De Diego, J., Lozano, M., et al. "Spray-casting ABPBI membranes for high temperature PEM fuel cells" . Journal of the Electrochemical Society, vol. 164, no. 7, 2017, pp. F866-F872.
http://dx.doi.org/10.1149/2.1621707jes
---------- VANCOUVER ----------
Viva, F., Heredia, N., Palmbaum, S.P., Diaz, L., De Diego, J., Lozano, M., et al. Spray-casting ABPBI membranes for high temperature PEM fuel cells. J Electrochem Soc. 2017;164(7):F866-F872.
http://dx.doi.org/10.1149/2.1621707jes