Artículo

Doumic, L.I.; Génova, M.; Žerjav, G.; Pintar, A.; Cassanello, M.C.; Romeo, H.E.; Ayude, M.A. "Hierarchically structured TiO 2 -based composites for Fenton-type oxidation processes" (2019) Journal of Environmental Management. 236:591-602
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Abstract:

A novel hierarchically structured composite aimed as a stable catalyst for the heterogeneous Fenton-type (HFT) oxidation process was developed by using a cost-effective and versatile technique. Prussian Blue nanoparticles (PBNP) were dispersed onto aligned macroporous TiO 2 (rutile) monoliths prepared via directional freezing of aqueous dispersions of TiO 2 nanoparticles. The catalytic performance was evaluated in the HFT oxidation of an azo dye frequently used as a model contaminant, Orange G (OG). Experiments were carried out in a liquid batch-recycle reactor, in which the liquid flow rate was set to ensure negligible external mass transfer resistance. The catalyst exhibited good activity to form highly oxidative radicals from hydrogen peroxide decomposition, which readily discolored OG. Significant reduction of the time required to attain complete discoloration and improvement in TOC removal were achieved by adjusting operating conditions and oxidant dosage strategies. Almost complete OG conversion at around 90 min and 34.4% of TOC removal after 4 h were achieved by using the best evaluated strategy. The catalyst activity was tested under specific operating conditions and remained unaltered during 42 cycles of 4 h each (total 168 h). The fresh and used PBNP/TiO 2 catalysts and the support were thoroughly characterized by several techniques. Results supported the excellent stability exhibited by the catalyst in the OG HFT oxidation. © 2019 Elsevier Ltd

Registro:

Documento: Artículo
Título:Hierarchically structured TiO 2 -based composites for Fenton-type oxidation processes
Autor:Doumic, L.I.; Génova, M.; Žerjav, G.; Pintar, A.; Cassanello, M.C.; Romeo, H.E.; Ayude, M.A.
Filiación:División Catalizadores y Superficies, INTEMA-CONICET, Departamento de Ingeniería Química, Facultad de Ingeniería, UNMdP, Av. Juan B. Justo 4302, Mar del Plata, B7608FDQ, Argentina
Department for Environmental Sciences and Engineering, National Institute of Chemistry, Hajdrihova 19, Ljubljana, SI-1001, Slovenia
LARSI, Dep. Industrias, FCEyN, Universidad de Buenos Aires, Int. Güiraldes 2620, Buenos Aires, C1428BGA, Argentina
División Polímeros Nanoestructurados, INTEMA-CONICET, Facultad de Ingeniería, UNMdP, Av. Juan B. Justo 4302, Mar del Plata, B7608FDQ, Argentina
Palabras clave:Heterogeneous Fenton-type oxidation; Hierarchically structured porous materials; Prussian Blue nanoparticles; Stability; ferrous gluconate; hydrogen peroxide; hydroxyl radical; organic compound; oxidizing agent; titanium dioxide; catalysis; catalyst; composite; dispersion; dye; experiment; hydrogen peroxide; mass transfer; nanoparticle; oxidation; oxide; porous medium; rutile; titanium; total organic carbon; adsorption; Article; catalyst; decomposition; Fenton reaction; field emission scanning electron microscopy; flow rate; Fourier transform infrared spectroscopy; heat treatment; hysteresis; liquid; mineralization; oxidation; porosity; surface area; temperature; thermogravimetry; X ray diffraction
Año:2019
Volumen:236
Página de inicio:591
Página de fin:602
DOI: http://dx.doi.org/10.1016/j.jenvman.2019.02.026
Título revista:Journal of Environmental Management
Título revista abreviado:J. Environ. Manage.
ISSN:03014797
CODEN:JEVMA
CAS:ferrous gluconate, 299-29-6; hydrogen peroxide, 7722-84-1; hydroxyl radical, 3352-57-6; titanium dioxide, 1317-70-0, 1317-80-2, 13463-67-7, 51745-87-0
Registro:http://digital.bl.fcen.uba.ar/collection/paper/document/paper_03014797_v236_n_p591_Doumic

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Citas:

---------- APA ----------
Doumic, L.I., Génova, M., Žerjav, G., Pintar, A., Cassanello, M.C., Romeo, H.E. & Ayude, M.A. (2019) . Hierarchically structured TiO 2 -based composites for Fenton-type oxidation processes. Journal of Environmental Management, 236, 591-602.
http://dx.doi.org/10.1016/j.jenvman.2019.02.026
---------- CHICAGO ----------
Doumic, L.I., Génova, M., Žerjav, G., Pintar, A., Cassanello, M.C., Romeo, H.E., et al. "Hierarchically structured TiO 2 -based composites for Fenton-type oxidation processes" . Journal of Environmental Management 236 (2019) : 591-602.
http://dx.doi.org/10.1016/j.jenvman.2019.02.026
---------- MLA ----------
Doumic, L.I., Génova, M., Žerjav, G., Pintar, A., Cassanello, M.C., Romeo, H.E., et al. "Hierarchically structured TiO 2 -based composites for Fenton-type oxidation processes" . Journal of Environmental Management, vol. 236, 2019, pp. 591-602.
http://dx.doi.org/10.1016/j.jenvman.2019.02.026
---------- VANCOUVER ----------
Doumic, L.I., Génova, M., Žerjav, G., Pintar, A., Cassanello, M.C., Romeo, H.E., et al. Hierarchically structured TiO 2 -based composites for Fenton-type oxidation processes. J. Environ. Manage. 2019;236:591-602.
http://dx.doi.org/10.1016/j.jenvman.2019.02.026