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Abstract:

We show that an azopolymer can be used to create a supramolecular architecture in a parallel process with patterned surface properties. By illuminating with an interference pattern, we created adhesion and charge patterns that reflect the molecular ordering. We studied the recording process in two limit situations. When birefringence dominates over mass transport, an adhesion pattern was recorded even in absence of a surface relief grating (SRG). When mass transport dominates, we measured a higher frequency adhesion and relief patterns on top of the SRG. We measured an increased negative charge in the regions where molecules are expected to be parallel aligned in trans conformational state. © 2019 Elsevier B.V.

Registro:

Documento: Artículo
Título:Functional surfaces through the creation of adhesion and charged patterns on azopolymer surface relief gratings
Autor:Capeluto, M.G.; Falcione, R.; Salvador, R.F.; Eceiza, A.; Goyanes, S.; Ledesma, S.A.
Filiación:Laboratorio de Procesado de Imágenes (LPI), Departamento de Física, Facultad de Ciencias Exactas y Naturales, Universidad de Buenos Aires and IFIBA, CONICET, Cuidad Universitaria, Buenos Aires, 1428, Argentina
Laboratorio de Polímeros y Materiales Compuestos (LPM&C), Departamento de Física, Facultad de Ciencias Exactas y Naturales, Universidad de Buenos Aires and IFIBA, CONICET, Cuidad Universitaria, Buenos Aires, 1428, Argentina
Grupo “Materiales + Tecnologías”, Departamento de Ingeniería Química y Del Medio Ambiente, Escuela de Ingeniería de Gipuzkoa, Universidad Del País Vasco, Pza. Europa 1, Donostia-San Sebastián, 20018, Spain
Palabras clave:Adhesion; Azopolymer; Functional surfaces; Surface relief gratings; Electrical engineering; Magnetic materials; Azopolymer; Conformational state; Functional surfaces; Higher frequencies; Interference patterns; Molecular ordering; Supramolecular architectures; Surface relief gratings; Adhesion
Año:2019
Volumen:90
Página de inicio:281
Página de fin:288
DOI: http://dx.doi.org/10.1016/j.optmat.2019.02.036
Título revista:Optical Materials
Título revista abreviado:Opt Mater
ISSN:09253467
CODEN:OMATE
Registro:http://digital.bl.fcen.uba.ar/collection/paper/document/paper_09253467_v90_n_p281_Capeluto

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Citas:

---------- APA ----------
Capeluto, M.G., Falcione, R., Salvador, R.F., Eceiza, A., Goyanes, S. & Ledesma, S.A. (2019) . Functional surfaces through the creation of adhesion and charged patterns on azopolymer surface relief gratings. Optical Materials, 90, 281-288.
http://dx.doi.org/10.1016/j.optmat.2019.02.036
---------- CHICAGO ----------
Capeluto, M.G., Falcione, R., Salvador, R.F., Eceiza, A., Goyanes, S., Ledesma, S.A. "Functional surfaces through the creation of adhesion and charged patterns on azopolymer surface relief gratings" . Optical Materials 90 (2019) : 281-288.
http://dx.doi.org/10.1016/j.optmat.2019.02.036
---------- MLA ----------
Capeluto, M.G., Falcione, R., Salvador, R.F., Eceiza, A., Goyanes, S., Ledesma, S.A. "Functional surfaces through the creation of adhesion and charged patterns on azopolymer surface relief gratings" . Optical Materials, vol. 90, 2019, pp. 281-288.
http://dx.doi.org/10.1016/j.optmat.2019.02.036
---------- VANCOUVER ----------
Capeluto, M.G., Falcione, R., Salvador, R.F., Eceiza, A., Goyanes, S., Ledesma, S.A. Functional surfaces through the creation of adhesion and charged patterns on azopolymer surface relief gratings. Opt Mater. 2019;90:281-288.
http://dx.doi.org/10.1016/j.optmat.2019.02.036