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Di Salvo, F.; Tsang, M.Y.; Teixidor, F.; Viñas, C.; Planas, J.G.; Crassous, J.; Vanthuyne, N.; Aliaga-Alcalde, N.; Ruiz, E.; Coquerel, G.; Clevers, S.; Dupray, V.; Choquesillo-Lazarte, D.; Light, M.E.; Hursthouse, M.B. "A racemic and enantiopure unsymmetric diiron(III) complex with a chiral o-carborane-based pyridylalcohol ligand: Combined chiroptical, magnetic, and nonlinear optical properties" (2014) Chemistry - A European Journal. 20(4):1081-1090
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Abstract:

The design of molecule-based systems combining magnetic, chiroptical and second-order optical nonlinear properties is still very rare. We report an unusually unsymmetric diiron(III) complex 1, in which three bulky chiral carboranylpyridinealkoxide ligands (oCBhmp-) bridge both metal ions and the complex shows the above-mentioned properties. The introduction of o-carborane into the 2-(hydroxymethyl)pyridine (hmpH) architecture significantly alters the coordination of the simple or aryl-substituted 2-hmpH. The unusual architecture observed in 1 seems to be triggered by the poor nucleophilicity of our alkoxide ligand (oCBhmp-). A very rare case of spontaneous resolution takes place on precipitation or exposure to solvent vapor for the bulk compound, as confirmed by a combination of single-crystal and powder X-ray diffraction, second-harmonic generation, and circular dichroism. The corresponding enantiopure complexes (+)1 and (-)1 have also been synthesized and fully characterized. This research provides a new building block with unique geometry and electronics to construct coordination complexes with multifunctional properties. Copyright © 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Registro:

Documento: Artículo
Título:A racemic and enantiopure unsymmetric diiron(III) complex with a chiral o-carborane-based pyridylalcohol ligand: Combined chiroptical, magnetic, and nonlinear optical properties
Autor:Di Salvo, F.; Tsang, M.Y.; Teixidor, F.; Viñas, C.; Planas, J.G.; Crassous, J.; Vanthuyne, N.; Aliaga-Alcalde, N.; Ruiz, E.; Coquerel, G.; Clevers, S.; Dupray, V.; Choquesillo-Lazarte, D.; Light, M.E.; Hursthouse, M.B.
Filiación:Institut de Ciència de Materials de Barcelona (ICMAB-CSIC), Campus U.A.B., 08193 Bellaterra, Spain
Departamento de Química Inorgánica, Analítica, y Química Física, Facultad de Ciencias Exactas y Naturales, Ciudad Universitaria, Pabellõn 2, C1428EHA Buenos Aires, Argentina
Institut des Sciences Chimiques de Rennes, Campus de Beaulieu, Université de Rennes 1, 35042 Rennes Cedex, France
Aix Marseille Université, Centrale Marseille, CNRS iSm2 UMR 7313, 13397 Marseille, France
Instituciõ Catalana de Recerca i Estudis Avançats (ICREA), Institut de Ciència de Materials de Barcelona (ICMAB-CSIC), Campus de la UAB, 08193 Bellaterra, Spain
Departament de Química Inorgànica, Institut de Recerca de Química Teòrica i Computacional, Universitat de Barcelona, Diagonal 647, 08028, Spain
Unite de Cristallogenese, Sciences et Methodes Separatives (SMS), Universite de ROUEN, Rue Tesniere, F-76821 Mont Saint-Aignan cedex, France
Laboratorio de Estudios Cristalográficos, IACT-CSIC, Armilla, Granada, Spain
School of Chemistry, University of Southampton, Highfield, Southampton, SO17 1BJ, United Kingdom
Department of Chemistry, Faculty of Science, King Abdulaziz University, Jeddah 21588, Saudi Arabia
Palabras clave:boron; chirality; iron; second-harmonic generation; spontaneous resolution; 2 pyridine(Hydroxymethyl); Coordination complex; Multifunctional properties; Non-linear optical properties; Optical nonlinear; Second-harmonic; Single-crystal and powder; Spontaneous resolution; Boron; Chirality; Iron; Ligands; Metal ions; Optical properties; Synthesis (chemical); Vapors; X ray diffraction; Stereochemistry
Año:2014
Volumen:20
Número:4
Página de inicio:1081
Página de fin:1090
DOI: http://dx.doi.org/10.1002/chem.201303037
Título revista:Chemistry - A European Journal
Título revista abreviado:Chem. Eur. J.
ISSN:09476539
CODEN:CEUJE
Registro:https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_09476539_v20_n4_p1081_DiSalvo

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Citas:

---------- APA ----------
Di Salvo, F., Tsang, M.Y., Teixidor, F., Viñas, C., Planas, J.G., Crassous, J., Vanthuyne, N.,..., Hursthouse, M.B. (2014) . A racemic and enantiopure unsymmetric diiron(III) complex with a chiral o-carborane-based pyridylalcohol ligand: Combined chiroptical, magnetic, and nonlinear optical properties. Chemistry - A European Journal, 20(4), 1081-1090.
http://dx.doi.org/10.1002/chem.201303037
---------- CHICAGO ----------
Di Salvo, F., Tsang, M.Y., Teixidor, F., Viñas, C., Planas, J.G., Crassous, J., et al. "A racemic and enantiopure unsymmetric diiron(III) complex with a chiral o-carborane-based pyridylalcohol ligand: Combined chiroptical, magnetic, and nonlinear optical properties" . Chemistry - A European Journal 20, no. 4 (2014) : 1081-1090.
http://dx.doi.org/10.1002/chem.201303037
---------- MLA ----------
Di Salvo, F., Tsang, M.Y., Teixidor, F., Viñas, C., Planas, J.G., Crassous, J., et al. "A racemic and enantiopure unsymmetric diiron(III) complex with a chiral o-carborane-based pyridylalcohol ligand: Combined chiroptical, magnetic, and nonlinear optical properties" . Chemistry - A European Journal, vol. 20, no. 4, 2014, pp. 1081-1090.
http://dx.doi.org/10.1002/chem.201303037
---------- VANCOUVER ----------
Di Salvo, F., Tsang, M.Y., Teixidor, F., Viñas, C., Planas, J.G., Crassous, J., et al. A racemic and enantiopure unsymmetric diiron(III) complex with a chiral o-carborane-based pyridylalcohol ligand: Combined chiroptical, magnetic, and nonlinear optical properties. Chem. Eur. J. 2014;20(4):1081-1090.
http://dx.doi.org/10.1002/chem.201303037