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Abstract:

Polybenzoxazines are a relatively new type of thermoset polymer that has primarily been used for the development of composite materials. However, there is an existing interest in expanding the applications for this family of polymers. One way of achieving this goal is by taking advantage of the molecular structure, where the presence of oxygen and nitrogen atoms with lone electron pairs allows the formation of coordination complexes and chelates between the benzoxazine oligomers and polymers with metal ions. This article is focused on studying the relationship between the spatial conformation of the polybenzoxazine and the capacity to form coordination complexes from a fundamental point of view as well as practical applications of this concept. Thus, it can be seen that use of polybenzoxazines for the removal of heavy metals from water and the use of benzoxazine dimers for the synthesis of CeO2 nanoparticles are examples of very different applications based on the same working principle. © 2018 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim

Registro:

Documento: Artículo
Título:Application of Benzoxazine-Based Dimers, Oligomers, and Polymers as Chelating Agents
Autor:Iguchi, D.; Salum, M.L.; Froimowicz, P.
Filiación:Design and Chemistry of Macromolecules Group, Institute of Technology in Polymers and Nanotechnology, UBA-CONICET, FIUBA, FADU, University of Buenos Aires, Ciudad Universitaria, Buenos Aires, 1428, Argentina
CIHIDECAR-CONICET, Departamento de Química Orgánica, Facultad de Ciencias Exactas y Naturales, Universidad de Buenos Aires, Ciudad Universitaria, Buenos Aires, 1428, Argentina
Palabras clave:chelate formation; heavy metal removal; nanoparticles; polybenzoxazines; Cerium oxide; Chelation; Coordination reactions; Dimers; Heavy metals; Metal ions; Metal nanoparticles; Molecular oxygen; Nanoparticles; Polymer blends; Synthesis (chemical); CeO2 nanoparticles; Chelate formation; Coordination complex; Heavy metal removal; Lone electron pair; Oxygen and nitrogens; polybenzoxazines; Spatial conformation; Chemicals removal (water treatment)
Año:2019
Volumen:220
Número:1
DOI: http://dx.doi.org/10.1002/macp.201800366
Título revista:Macromolecular Chemistry and Physics
Título revista abreviado:Macromol. Chem. Phys.
ISSN:10221352
CODEN:MCHPE
Registro:http://digital.bl.fcen.uba.ar/collection/paper/document/paper_10221352_v220_n1_p_Iguchi

Referencias:

  • Ishida, H., Agag, T., (2011) Handbook of Benzoxazine Resins, , Elsevier, Amsterdam
  • Kiskan, B., Ghosh, N.N., Yagci, Y., (2011) Polym. Int., 60, p. 167
  • Ghosh, N.N., Kiskan, B., Yagci, Y., (2007) Prog. Polym. Sci., 32, p. 1344
  • Yagci, Y., Kiskan, B., Ghosh, N., (2009) J. Polym. Sci., Part A: Polym. Chem., 47, p. 5565
  • Rimdusit, S., Tiptipakorn, S., Jubsilp, C., Takeichi, T., (2013) React. Funct. Polym., 73, p. 369
  • Demir, K.D., Kiskan, B., Aydogan, B., Yagci, Y., (2013) React. Funct. Polym., 73, p. 346
  • Kim, H.D., Ishida, H., (2001) J. Appl. Polym. Sci., 79, p. 1207
  • Shyan, B.S., Ishida, H., (1996) Polym. Compos., 17, p. 710
  • Nair, C.P.R., (2004) Prog. Polym. Sci., 29, p. 401
  • Ching, H.L., Sheng, X.C., Tsu, S.L., Ting, Y.H., L Hao, H., (2006) J. Polym. Sci., Part A: Polym. Chem., 44, p. 3454
  • Ishida, H., Allen, D.J., (1996) J. Polym. Sci., Part B: Polym. Phys., 34, p. 1019
  • Velez-Herrera, P., Doyama, K., Abe, H., Ishida, H., (2008) Macromolecules, 41, p. 9704
  • Xu, Q., Zeng, M., Chen, J., Zeng, S., Huang, Y., Feng, Z., Xu, Q., Gu, Y., (2018) React. Funct. Polym., 122, p. 158
  • Froimowicz, P., Zhang, K., Ishida, H., (2016) Chem. - Eur. J., 22, p. 2691
  • Dayo, A.Q., Gao, B.-C., Wang, J., Liu, W.-B., Derradji, M., Shah, A.H., Babar, A.A., (2017) Compos. Sci. Technol., 144, p. 114
  • Kajohnchaiyagual, J., Jubsilp, C., Dueramae, I., Rimdusit, S., (2014) Polym. Compos., 35, p. 2269
  • Li, N., Yan, H., Xia, L., Mao, L., Fang, Z., Song, Y., Wang, H., (2015) Compos. Sci. Technol., 121, p. 82
  • Gruber, U.F., (1969) Blood Replacement, p. 157
  • Aebi, H., (1974) Methods of Enzymatic Analysis, p. 673. , 2nd ed. (Ed, H. U. Bergmeyer, Academic Press Inc., New York, p
  • Fujita, K.-I., Kawahara, R., Aikawa, T., Yamaguchi, R., (2015) Angew. Chem., Int. Ed., 54, p. 9057
  • Finn, M., Ridenour, J.A., Heltzel, J., Cahill, C., Voutchkova-Kostal, A., (2018) Organometallics, 37, p. 1400
  • Ma, Z., Moulton, B., (2011) Coord. Chem. Rev., 255, p. 1623
  • Sun, R.W.Y., Ma, D.-L., Wong, E.L.M., Che, C.-M., (2007) Dalton Trans., p. 4884
  • Liu, J.-F., Zhao, Z.-S., Jiang, G.-B., (2008) Environ. Sci. Technol., 42, p. 6949
  • Maketon, W., Zenner, C.Z., Ogden, K.L., (2008) Environ. Sci. Technol., 42, p. 2124
  • Li, W., Jia, X., (2017) Advanced and Emerging Polybenzoxazine Science and Technology, p. 245. , (Ed, P. Froimowicz, Elsevier, Amsterdam, p
  • Rajput, A.B., Rahaman, S.J., Sarkhel, G., Patra, M.K., Vadera, S.R., Singru, P.M., Yagci, Y., Ghosh, N.N., (2013) J. Appl. Polym. Sci., 128, p. 3726
  • Kiskan, B., Demirel, A.L., Kamer, O., Yagci, Y., (2008) J. Polym. Sci., Part A: Polym. Chem., 46, p. 6780
  • Tuzun, A., Kiskan, B., Alemdar, N., Erciyes, A.T., Yagci, Y., (2010) J. Polym. Sci., Part A: Polym. Chem., 48, p. 4279
  • Kaewvilai, A., Wattanathana, W., Jongrungruangchok, S., Veranitisagul, C., Koonsaeng, N., Laobuthee, A., (2015) Mater. Chem. Phys., 167, p. 9
  • Shen, D., Liu, C., Sebastián, R.M., Marquet, J., Schönfeld, R., (2016) J. Appl. Polym. Sci., 133, p. 44099
  • Exner, O., (1997) Chemom. Intell. Lab. Syst., 39, p. 85
  • Phongtamrug, S., Pulpoka, B., Chirachanchai, S., (2004) Supramol. Chem., 16, p. 269
  • Han, L., Iguchi, D., Gil, P., Heyl, T.R., Sedwick, V.M., Arza, C.R., Ohashi, S., Ishida, H., (2017) J. Phys. Chem. A, 121, p. 6269
  • Chirachanchai, S., Laobuthee, A., Phongtamrug, S., Siripatanasarakit, W., Ishida, H., (2000) J. Appl. Polym. Sci., 77, p. 2561
  • Goward, G.R., Sebastiani, D., Schnell, I., Spiess, H.W., Kim, H.-D., Ishida, H., (2003) J. Am. Chem. Soc., 125, p. 5792
  • Kim, H.D., Ishida, H., (2003) Macromol. Symp., 195, p. 123
  • Chaisuwan, T., Komalwanich, T., Luangsukrerk, S., Wongkasemjit, S., (2010) Desalination, 256, p. 108
  • Taskin Omer, S., Kiskan, B., Aksu, A., Balkis, N., Weber, J., Yagci, Y., (2014) Chem. - Eur. J., 20, p. 10953
  • Lavoie, R.A., Jardine, T.D., Chumchal, M.M., Kidd, K.A., Campbell, L.M., (2013) Environ. Sci. Technol., 47, p. 13385
  • Hutcheson, M.S., Smith, C.M., Rose, J., Batdorf, C., Pancorbo, O., West, C.R., Strube, J., Francis, C., (2014) Environ. Sci. Technol., 48, p. 2193
  • Grandjean, P., Weihe, P., White, R.F., Debes, F., Araki, S., Yokoyama, K., Murata, K., JØgensen, P.J., (1997) Neurotoxicol. Teratol., 19, p. 417
  • Järup, L., (2003) Br. Med. Bull., 68, p. 167
  • Tchounwou, P., Ayensu, W., Ninashvili, N., Sutton, D., (2003) Environ. Toxicol., 18, p. 149
  • Dana, R.K., Iver, W.D., Donald, N.C., Ricardo, M.P., (1967) Limnol. Oceanogr., 12, p. 176
  • Akay, S., Kayan, B., Kalderis, D., Arslan, M., Yagci, Y., Kiskan, B., (2017) J. Appl. Polym. Sci., 134, p. 45306
  • Cotton, F.A., Wilkinson, G., (1972) Advanced Inorganic Chemistry, p. 596. , 3rd edition,, Wiley, New York
  • Veranitisagul, C., Kaewvilai, A., Sangngern, S., Wattanathana, W., Suramitr, S., Koonsaeng, N., Laobuthee, A., (2011) Int. J. Mol. Sci., 12, p. 4365
  • Bosque-Sendra, J., Almansa-López, E., García-Campaña, A.M., Cuadros-Rodríguez, L., (2003) Anal. Sci., 19, p. 1431

Citas:

---------- APA ----------
Iguchi, D., Salum, M.L. & Froimowicz, P. (2019) . Application of Benzoxazine-Based Dimers, Oligomers, and Polymers as Chelating Agents. Macromolecular Chemistry and Physics, 220(1).
http://dx.doi.org/10.1002/macp.201800366
---------- CHICAGO ----------
Iguchi, D., Salum, M.L., Froimowicz, P. "Application of Benzoxazine-Based Dimers, Oligomers, and Polymers as Chelating Agents" . Macromolecular Chemistry and Physics 220, no. 1 (2019).
http://dx.doi.org/10.1002/macp.201800366
---------- MLA ----------
Iguchi, D., Salum, M.L., Froimowicz, P. "Application of Benzoxazine-Based Dimers, Oligomers, and Polymers as Chelating Agents" . Macromolecular Chemistry and Physics, vol. 220, no. 1, 2019.
http://dx.doi.org/10.1002/macp.201800366
---------- VANCOUVER ----------
Iguchi, D., Salum, M.L., Froimowicz, P. Application of Benzoxazine-Based Dimers, Oligomers, and Polymers as Chelating Agents. Macromol. Chem. Phys. 2019;220(1).
http://dx.doi.org/10.1002/macp.201800366