Artículo

Oestreicher, V.; Jobbágy, M."Extremely efficient crystallization of HKUST-1 and Keggin-loaded related phases through the epoxide route" (2017) Chemical Communications. 53(24):3466-3468
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Abstract:

Highly crystalline HKUST-1 and COK-16-like phases were obtained based on a mild in situ alkalinization one-pot epoxide driven method. A slurry composed of finely ground trimesic acid, H3BTC, dispersed in a CuCl2 aqueous solution quantitatively developed well crystallized HKUST-1 after the addition of propylene oxide. The use of solid H3BTC ensures a low concentration of free linker, favoring crystalline growth over the precipitation of amorphous or metastable impurities. An extreme space-time yield of 2.1 × 105 kg m-3 day-1 was reached, with no linker excess and minimum use of solvent. The method was equally efficient in the achievement of pure NENU/COK-16 phases, containing [PW12O40]3-, [PMo12O40]3- and [SiMo12O40]4- polyoxometalates. © The Royal Society of Chemistry.

Registro:

Documento: Artículo
Título:Extremely efficient crystallization of HKUST-1 and Keggin-loaded related phases through the epoxide route
Autor:Oestreicher, V.; Jobbágy, M.
Filiación:INQUIMAE-DQIAQF, Facultad de Ciencias Exactas y Naturales, Universidad de Buenos Aires. Ciudad Universitaria, Pab. II, C1428EHA, Buenos Aires, Argentina
Centro Interdisciplinario de Nanociencia y Nanotecnología, Argentina
Palabras clave:copper chloride; epoxide; nitrogen; propylene oxide; adsorption; alkalinization; aqueous solution; Article; crystallization; desorption; one pot synthesis; precipitation
Año:2017
Volumen:53
Número:24
Página de inicio:3466
Página de fin:3468
DOI: http://dx.doi.org/10.1039/c7cc00737j
Handle:http://hdl.handle.net/20.500.12110/paper_13597345_v53_n24_p3466_Oestreicher
Título revista:Chemical Communications
Título revista abreviado:Chem. Commun.
ISSN:13597345
CODEN:CHCOF
CAS:copper chloride, 1344-67-8; nitrogen, 7727-37-9; propylene oxide, 75-56-9
Registro:https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_13597345_v53_n24_p3466_Oestreicher

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Citas:

---------- APA ----------
Oestreicher, V. & Jobbágy, M. (2017) . Extremely efficient crystallization of HKUST-1 and Keggin-loaded related phases through the epoxide route. Chemical Communications, 53(24), 3466-3468.
http://dx.doi.org/10.1039/c7cc00737j
---------- CHICAGO ----------
Oestreicher, V., Jobbágy, M. "Extremely efficient crystallization of HKUST-1 and Keggin-loaded related phases through the epoxide route" . Chemical Communications 53, no. 24 (2017) : 3466-3468.
http://dx.doi.org/10.1039/c7cc00737j
---------- MLA ----------
Oestreicher, V., Jobbágy, M. "Extremely efficient crystallization of HKUST-1 and Keggin-loaded related phases through the epoxide route" . Chemical Communications, vol. 53, no. 24, 2017, pp. 3466-3468.
http://dx.doi.org/10.1039/c7cc00737j
---------- VANCOUVER ----------
Oestreicher, V., Jobbágy, M. Extremely efficient crystallization of HKUST-1 and Keggin-loaded related phases through the epoxide route. Chem. Commun. 2017;53(24):3466-3468.
http://dx.doi.org/10.1039/c7cc00737j