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Abstract:

Highly crystalline HKUST-1 and COK-16-like phases were obtained based on a mild in situ alkalinization one-pot epoxide driven method. A slurry composed of finely ground trimesic acid, H3BTC, dispersed in a CuCl2 aqueous solution quantitatively developed well crystallized HKUST-1 after the addition of propylene oxide. The use of solid H3BTC ensures a low concentration of free linker, favoring crystalline growth over the precipitation of amorphous or metastable impurities. An extreme space-time yield of 2.1 × 105 kg m-3 day-1 was reached, with no linker excess and minimum use of solvent. The method was equally efficient in the achievement of pure NENU/COK-16 phases, containing [PW12O40]3-, [PMo12O40]3- and [SiMo12O40]4- polyoxometalates. © The Royal Society of Chemistry.

Registro:

Documento: Artículo
Título:Extremely efficient crystallization of HKUST-1 and Keggin-loaded related phases through the epoxide route
Autor:Oestreicher, V.; Jobbágy, M.
Filiación:INQUIMAE-DQIAQF, Facultad de Ciencias Exactas y Naturales, Universidad de Buenos Aires. Ciudad Universitaria, Pab. II, C1428EHA, Buenos Aires, Argentina
Centro Interdisciplinario de Nanociencia y Nanotecnología, Argentina
Palabras clave:copper chloride; epoxide; nitrogen; propylene oxide; adsorption; alkalinization; aqueous solution; Article; crystallization; desorption; one pot synthesis; precipitation
Año:2017
Volumen:53
Número:24
Página de inicio:3466
Página de fin:3468
DOI: http://dx.doi.org/10.1039/c7cc00737j
Título revista:Chemical Communications
Título revista abreviado:Chem. Commun.
ISSN:13597345
CODEN:CHCOF
CAS:copper chloride, 1344-67-8; nitrogen, 7727-37-9; propylene oxide, 75-56-9
Registro:https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_13597345_v53_n24_p3466_Oestreicher

Referencias:

  • Baccile, N., Babonneau, F., Thomas, B., Coradin, T., (2009) J. Mater. Chem., 19, pp. 8537-8559
  • Jammaer, J., Van Erp, T.S., Aerts, A., Kirschhock, C.E.A., Martens, J.A., (2011) J. Am. Chem. Soc., 133, pp. 13737-13745
  • Pini, M., Rosa, R., Neri, P., Bondioli, F., Ferrari, A.M., (2015) Green Chem., 17, pp. 518-531
  • Czaja, A.U., Trukhan, N., Müller, U., (2009) Chem. Soc. Rev., 38, pp. 1284-1293
  • Chui, S.S.Y., Lo, S.M.F., Charmant, J.P.H., Orpen, A.G., Williams, I.D., (1999) Science, 283, pp. 1148-1150
  • Alaerts, L., Seguin, E., Poelman, H., Thibault-Starzyk, F., Jacobs, P.A., De Vos, D.E., (2006) Chem.-Eur. J., 12, pp. 7353-7363
  • Müller, U., Hesse, M., Puetter, H., Schubert, M., Wessel, H., Hu, J., Marcus, G., (2011), US Pat., US; Majano, G., Pérez-Ramírez, J., (2013) Adv. Mater., 25, pp. 1052-1057
  • Majano, G., Ingold, O., Yulikov, M., Jeschke, G., Perez-Ramirez, J., (2013) CrystEngComm, 15, pp. 9885-9892
  • Huo, J., Brightwell, M., El Hankari, S., Garai, A., Bradshaw, D., (2013) J. Mater. Chem. A, 1, pp. 15220-15223
  • Crawford, D., Casaban, J., Haydon, R., Giri, N., McNally, T., James, S.L., (2015) Chem. Sci., 6, pp. 1645-1649
  • Gash, A.E., Tillotson, T.M., Satcher, J.H., Poco, J.F., Hrubesh, L.W., Simpson, R.L., (2001) Chem. Mater., 13, pp. 999-1007
  • Yang, L., Naruke, H., Yamase, T., (2003) Inorg. Chem. Commun., 6, pp. 1020-1024
  • Sun, C.Y., Liu, S.X., Liang, D.D., Shao, K.Z., Ren, Y.H., Su, Z.M., (2009) J. Am. Chem. Soc., 131, pp. 1883-1888
  • Mustafa, D., Breynaert, E., Bajpe, S.R., Martens, J.A., Kirschhock, C.E.A., (2011) Chem. Commun., 47, pp. 8037-8039
  • Oestreicher, V., Jobbágy, M., (2013) Langmuir, 29, pp. 12104-12109
  • Bajpe, S.R., Kirschhock, C.E.A., Aerts, A., Breynaert, E., Absillis, G., Parac-Vogt, T.N., Giebeler, L., Martens, J.A., (2010) Chem.-Eur. J., 16, pp. 3926-3932
  • Oestreicher, V., Fábregas, I., Jobbágy, M., (2014) J. Phys. Chem. C, 118, pp. 30274-30281
  • Oestreicher, V., Perullini, M., Jobbágy, M., (2016) Dalton Trans., 45, pp. 9920-9924
  • Jiménez-González, C., Constable, D.J.C., Ponder, C.S., (2012) Chem. Soc. Rev., 41, pp. 1485-1498
  • Sheldon, R.A., (2017) Green Chem., 19, pp. 18-43
  • Kahlich, D., Wiechern, U., Lindner, J., (2011) Ullmann's Encyclopedia of Industrial Chemistry

Citas:

---------- APA ----------
Oestreicher, V. & Jobbágy, M. (2017) . Extremely efficient crystallization of HKUST-1 and Keggin-loaded related phases through the epoxide route. Chemical Communications, 53(24), 3466-3468.
http://dx.doi.org/10.1039/c7cc00737j
---------- CHICAGO ----------
Oestreicher, V., Jobbágy, M. "Extremely efficient crystallization of HKUST-1 and Keggin-loaded related phases through the epoxide route" . Chemical Communications 53, no. 24 (2017) : 3466-3468.
http://dx.doi.org/10.1039/c7cc00737j
---------- MLA ----------
Oestreicher, V., Jobbágy, M. "Extremely efficient crystallization of HKUST-1 and Keggin-loaded related phases through the epoxide route" . Chemical Communications, vol. 53, no. 24, 2017, pp. 3466-3468.
http://dx.doi.org/10.1039/c7cc00737j
---------- VANCOUVER ----------
Oestreicher, V., Jobbágy, M. Extremely efficient crystallization of HKUST-1 and Keggin-loaded related phases through the epoxide route. Chem. Commun. 2017;53(24):3466-3468.
http://dx.doi.org/10.1039/c7cc00737j