Artículo

Arencibia, N.; Oestreicher, V.; Viva, F.A.; Jobbágy, M."Nanotextured alpha Ni(II)-Co(II) hydroxides as supercapacitive active phases" (2017) RSC Advances. 7(10):5595-5600
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Abstract:

A family of monophasic nanoplatelets of Ni(ii)-Co(ii) layered hydroxides, were obtained by a one-pot room temperature homogeneous alkalinization driven by the the epoxide route with glycidol. Both cations precipitate in the form of solid solutions, giving the general formula Ni1-xCox(OH)2-yCly·nH2O. Co(ii)-rich samples developed the simonkolleite-like alpha structure in which cations can adopt either octahedral (Oh) or tetrahedral (Td) environments, according to the formula (Ni,Co)Oh1-xCoTd2x(OH)2-2x(Cl)2x·nH2O. Ni(ii)-rich ones resulted in ill-crystallized turbostratic (Ni,Co)1-x(OH)2-x(Cl)x·nH2O. Despite the inherent differences in the crystallochemical nature of theses phases, electrochemical measurements depict a monotonous behavior in terms of their capacitance. An optimum performance was observed for samples with XNi(II) = 0.83 under most of the experimental conditions explored. This sample reaches a maximum specific capacitance of 2091 F g-1, registered at a discharge current density of 0.5 A g-1, while an energy density of 80.7 W h kg-1 was recorded at a power density of 960.4 W kg-1. © 2017 The Royal Society of Chemistry.

Registro:

Documento: Artículo
Título:Nanotextured alpha Ni(II)-Co(II) hydroxides as supercapacitive active phases
Autor:Arencibia, N.; Oestreicher, V.; Viva, F.A.; Jobbágy, M.
Filiación:INQUIMAE-DQIAQF, Facultad de Ciencias Exactas y Naturales, Universidad de Buenos Aires, Ciudad Universitaria Pab. II C1428EHA, Buenos Aires, Argentina
Departamento de Física de la Materia Condensada, Centro Atómico Constituyentes, Comisión Nacional de Energía Atómica, Av. General Paz 1499, Buenos Aires, B1650KNA, Argentina
Centro Interdisciplinario de Nanociencia y Nanotecnología, Argentina
Palabras clave:Capacitance; Positive ions; Discharge current density; Electrochemical measurements; Experimental conditions; General formulas; Homogeneous alkalinization; Layered hydroxides; Optimum performance; Specific capacitance; Nickel
Año:2017
Volumen:7
Número:10
Página de inicio:5595
Página de fin:5600
DOI: http://dx.doi.org/10.1039/c6ra27839f
Handle:http://hdl.handle.net/20.500.12110/paper_20462069_v7_n10_p5595_Arencibia
Título revista:RSC Advances
Título revista abreviado:RSC Adv.
ISSN:20462069
CODEN:RSCAC
Registro:https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_20462069_v7_n10_p5595_Arencibia

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Citas:

---------- APA ----------
Arencibia, N., Oestreicher, V., Viva, F.A. & Jobbágy, M. (2017) . Nanotextured alpha Ni(II)-Co(II) hydroxides as supercapacitive active phases. RSC Advances, 7(10), 5595-5600.
http://dx.doi.org/10.1039/c6ra27839f
---------- CHICAGO ----------
Arencibia, N., Oestreicher, V., Viva, F.A., Jobbágy, M. "Nanotextured alpha Ni(II)-Co(II) hydroxides as supercapacitive active phases" . RSC Advances 7, no. 10 (2017) : 5595-5600.
http://dx.doi.org/10.1039/c6ra27839f
---------- MLA ----------
Arencibia, N., Oestreicher, V., Viva, F.A., Jobbágy, M. "Nanotextured alpha Ni(II)-Co(II) hydroxides as supercapacitive active phases" . RSC Advances, vol. 7, no. 10, 2017, pp. 5595-5600.
http://dx.doi.org/10.1039/c6ra27839f
---------- VANCOUVER ----------
Arencibia, N., Oestreicher, V., Viva, F.A., Jobbágy, M. Nanotextured alpha Ni(II)-Co(II) hydroxides as supercapacitive active phases. RSC Adv. 2017;7(10):5595-5600.
http://dx.doi.org/10.1039/c6ra27839f