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Baraldo, L.M.; Forlano, P.; Parise, A.R.; Slep, L.D.; Olabe, J.A. "Advances in the coordination chemistry of [M(CN)5L]n- ions (M = Fe, Ru, Os)" (2001) Coordination Chemistry Reviews. 219-221:881-921
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Abstract:

New developments in the synthesis, crystal and molecular structure, spectroscopy and kinetic properties of the [M(CN)5L]n- ions (MH11,111 = Fe, Ru, Os; L = H2O, NH3, amines, CN-, N-heterocyclic ligands, etc.), performed over the last decade, are reviewed. The properties of dinuclear complexes containing pentacyano-fragments bridged by pyrazine, cyanide or other bridging ligands, are also considered, with emphasis on mixed-valent systems. The influence of the solvent and other medium effects on the electronic structure, as well as on the modification of the reactivity of L upon coordination is addressed particularly. Some catalytic processes relevant to bioinorganic chemistry are discussed, involving either ligand oxidation (hydrazine, thiolates) or reduction (nitrosyl). © 2001 Elsevier Science B.V. All rights reserved.

Registro:

Documento: Artículo
Título:Advances in the coordination chemistry of [M(CN)5L]n- ions (M = Fe, Ru, Os)
Autor:Baraldo, L.M.; Forlano, P.; Parise, A.R.; Slep, L.D.; Olabe, J.A.
Filiación:Departamento de Química Inorgánica, Analítica y Química Física, Facultad de Ciencias Exactas y Naturales, Universidad de Buenos Aires, Pabellón 2, C1428EHA Buenos Aires, Argentina
Palabras clave:Cyanide-bridged systems; Mixed-valent complexes; Pentacyano-L-metalates; Reactions of coordinated ligands; coordination compound; cyanide; hydrazine; iron derivative; ligand; osmium derivative; pyrazine; ruthenium derivative; catalysis; chemical structure; complex formation; crystallography; electron transport; oxidation; review; spectroscopy; synthesis
Año:2001
Volumen:219-221
Página de inicio:881
Página de fin:921
DOI: http://dx.doi.org/10.1016/S0010-8545(01)00383-6
Título revista:Coordination Chemistry Reviews
Título revista abreviado:Coord. Chem. Rev.
ISSN:00108545
CODEN:CCHRA
Registro:https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00108545_v219-221_n_p881_Baraldo

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Citas:

---------- APA ----------
Baraldo, L.M., Forlano, P., Parise, A.R., Slep, L.D. & Olabe, J.A. (2001) . Advances in the coordination chemistry of [M(CN)5L]n- ions (M = Fe, Ru, Os). Coordination Chemistry Reviews, 219-221, 881-921.
http://dx.doi.org/10.1016/S0010-8545(01)00383-6
---------- CHICAGO ----------
Baraldo, L.M., Forlano, P., Parise, A.R., Slep, L.D., Olabe, J.A. "Advances in the coordination chemistry of [M(CN)5L]n- ions (M = Fe, Ru, Os)" . Coordination Chemistry Reviews 219-221 (2001) : 881-921.
http://dx.doi.org/10.1016/S0010-8545(01)00383-6
---------- MLA ----------
Baraldo, L.M., Forlano, P., Parise, A.R., Slep, L.D., Olabe, J.A. "Advances in the coordination chemistry of [M(CN)5L]n- ions (M = Fe, Ru, Os)" . Coordination Chemistry Reviews, vol. 219-221, 2001, pp. 881-921.
http://dx.doi.org/10.1016/S0010-8545(01)00383-6
---------- VANCOUVER ----------
Baraldo, L.M., Forlano, P., Parise, A.R., Slep, L.D., Olabe, J.A. Advances in the coordination chemistry of [M(CN)5L]n- ions (M = Fe, Ru, Os). Coord. Chem. Rev. 2001;219-221:881-921.
http://dx.doi.org/10.1016/S0010-8545(01)00383-6