Artículo
Albores, P.; Slep, L.D.; Baraldo, L.M.; Baggio, R.; Garland, M.T.; Rentschler, E. "Crystal structure and electronic and magnetic properties of hexacyanoosmate(III)" (2006) Inorganic Chemistry. 45(6):2361-2363
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Abstract:
The [OsIII(CN)6]3- anion is prepared by chemical oxidation in aqueous solution and isolated as yellow prisms of [Ph 4P]3[OsIII(CN)6]·6H 2O (1). This species crystallizes in the triclinic space group P1 with cell parameters a = 13.7609(11) Å, b = 16.2275(13) Å, c = 17.0895(14) Å, α = 91.4040(10)°, β = 109.3600(10)°, γ = 102.3970(10)°, V = 3497.4(5) Å3, and Z = 2. The slightly distorted octahedral moiety displays Os-C and C-N bond lengths that average 2.058 and 1.146 Å, respectively. Spin-orbit-coupling splitting of the ground-state term dominates the NIR region of the electronic spectrum and the magnetic behavior of 1. The experimental information points to higher spin delocalization over the coordinated cyanides than in [FeIII(CN) 6]3-. © 2006 American Chemical Society.
Registro:
| Documento: | Artículo |
| Título: | Crystal structure and electronic and magnetic properties of hexacyanoosmate(III) |
| Autor: | Albores, P.; Slep, L.D.; Baraldo, L.M.; Baggio, R.; Garland, M.T.; Rentschler, E. |
| Filiación: | Departamento de Química Inorgánica, Analítica Y Química Física, INQUIMAE, Ciudad Universitaria, C1428EHA, Buenos Aires, Argentina Comisión Nacional de Energía Atómica (CNEA), Av. Gral Paz 1499, 1650 S. Martin, Pcia. de Buenos Aires, Argentina Departamento de Física, Facultad de Ciencias Físicas Y Matemáticas, Universidad de Chile, Ave. Blanco Encalada 2008, C. 487-3, Santiago, Chile Institute of Inorganic and Analytical Chemistry, Johannes Gutenberg - University of Mainz, Duesbergweg 10-14, D-55128 Mainz, Germany |
| Año: | 2006 |
| Volumen: | 45 |
| Número: | 6 |
| Página de inicio: | 2361 |
| Página de fin: | 2363 |
| DOI: | http://dx.doi.org/10.1021/ic0516818 |
| Título revista: | Inorganic Chemistry |
| Título revista abreviado: | Inorg. Chem. |
| ISSN: | 00201669 |
| CODEN: | INOCA |
| Registro: | https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00201669_v45_n6_p2361_Albores |
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Citas:
---------- APA ----------
Albores, P., Slep, L.D., Baraldo, L.M., Baggio, R., Garland, M.T. & Rentschler, E. (2006) . Crystal structure and electronic and magnetic properties of hexacyanoosmate(III). Inorganic Chemistry, 45(6), 2361-2363.http://dx.doi.org/10.1021/ic0516818
---------- CHICAGO ----------
Albores, P., Slep, L.D., Baraldo, L.M., Baggio, R., Garland, M.T., Rentschler, E. "Crystal structure and electronic and magnetic properties of hexacyanoosmate(III)" . Inorganic Chemistry 45, no. 6 (2006) : 2361-2363.http://dx.doi.org/10.1021/ic0516818
---------- MLA ----------
Albores, P., Slep, L.D., Baraldo, L.M., Baggio, R., Garland, M.T., Rentschler, E. "Crystal structure and electronic and magnetic properties of hexacyanoosmate(III)" . Inorganic Chemistry, vol. 45, no. 6, 2006, pp. 2361-2363.http://dx.doi.org/10.1021/ic0516818
---------- VANCOUVER ----------
Albores, P., Slep, L.D., Baraldo, L.M., Baggio, R., Garland, M.T., Rentschler, E. Crystal structure and electronic and magnetic properties of hexacyanoosmate(III). Inorg. Chem. 2006;45(6):2361-2363.http://dx.doi.org/10.1021/ic0516818
