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Abstract:

We are reporting new dimeric units of basic carboxylates bearing the {Fe III 2M IIO} motif for M = Co and Ni, covalently bound through the tetradentate bridging (LL) 2,2′-azopyiridine (azpy) and 2,3-di(2-pyridyl)quinoxaline ligands (dpq). We structurally characterized the hexanuclear clusters, and their magnetic properties have been fully analyzed. DFT calculations have been performed as a supplementary tool. All results evidence a weak antiferromagnetic interaction through the bridging ligands between isolated spin ground states arising from intra-Fe 2MO core exchange couplings. Together with the pioneer 2,2′-bipyrimidine bridged systems, the new complexes reported constitute a family of complexes where the exchange interaction can be tuned by the selection of the bridging LL type ligand. © 2012 American Chemical Society.

Registro:

Documento: Artículo
Título:Tailoring the exchange interaction in covalently linked basic carboxylate clusters through bridging ligand selection
Autor:Alborés, P.; Plenk, C.; Rentschler, E.
Filiación:Institute of Inorganic and Analytical Chemistry, Johannes Gutenberg - University of Mainz, Duesbergweg 10-14, D-55128 Mainz, Germany
Departamento de Química Inorgánica, Analítica y Química Física, Facultad de Ciencias Exactas y Naturales, Universidad de Buenos Aires, Pabellón 2, C1428EHA Buenos Aires, Argentina
Año:2012
Volumen:51
Número:15
Página de inicio:8373
Página de fin:8384
DOI: http://dx.doi.org/10.1021/ic300911j
Título revista:Inorganic Chemistry
Título revista abreviado:Inorg. Chem.
ISSN:00201669
CODEN:INOCA
Registro:https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00201669_v51_n15_p8373_Albores

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Citas:

---------- APA ----------
Alborés, P., Plenk, C. & Rentschler, E. (2012) . Tailoring the exchange interaction in covalently linked basic carboxylate clusters through bridging ligand selection. Inorganic Chemistry, 51(15), 8373-8384.
http://dx.doi.org/10.1021/ic300911j
---------- CHICAGO ----------
Alborés, P., Plenk, C., Rentschler, E. "Tailoring the exchange interaction in covalently linked basic carboxylate clusters through bridging ligand selection" . Inorganic Chemistry 51, no. 15 (2012) : 8373-8384.
http://dx.doi.org/10.1021/ic300911j
---------- MLA ----------
Alborés, P., Plenk, C., Rentschler, E. "Tailoring the exchange interaction in covalently linked basic carboxylate clusters through bridging ligand selection" . Inorganic Chemistry, vol. 51, no. 15, 2012, pp. 8373-8384.
http://dx.doi.org/10.1021/ic300911j
---------- VANCOUVER ----------
Alborés, P., Plenk, C., Rentschler, E. Tailoring the exchange interaction in covalently linked basic carboxylate clusters through bridging ligand selection. Inorg. Chem. 2012;51(15):8373-8384.
http://dx.doi.org/10.1021/ic300911j