Artículo
Pieslinger, G.E.; Albores, P.; Slep, L.D.; Coe, B.J.; Timpson, C.J.; Baraldo, L.M. "Communication between remote moieties in linear Ru-Ru-Ru trimetallic cyanide-bridged complexes" (2013) Inorganic Chemistry. 52(6):2906-2917
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Abstract:
In this article, we report the structural, spectroscopic, and electrochemical properties of the cyanide-bridged complex salts trans-[(NC)RuII(L)4(μ-CN)RuII(py) 4Cl]PF6 and trans-[RuII(L)4{(μ- CN)RuII(py)4Cl}2](PF6)2 (L = pyridine or 4-methoxypyridine). The mixed-valence forms of these compounds show a variety of metal-to-metal charge-transfer bands, including one arising from charge transfer between the remote ruthenium units. The latter is more intense when L = 4-methoxypyridine and points to the role of the bridging ruthenium unit in promoting mixing between the dπ orbitals of the terminal fragments. © 2013 American Chemical Society.
Registro:
| Documento: | Artículo |
| Título: | Communication between remote moieties in linear Ru-Ru-Ru trimetallic cyanide-bridged complexes |
| Autor: | Pieslinger, G.E.; Albores, P.; Slep, L.D.; Coe, B.J.; Timpson, C.J.; Baraldo, L.M. |
| Filiación: | Departamento de Química Inorgánica, Analítica y Química Física, Facultad de Ciencias Exactas y Naturales, Universidad de Buenos Aires, Pabellón 2, 3 piso, C1428EHA Buenos Aires, Argentina Department of Chemistry, University of Manchester, Oxford Road, Manchester M13 9PL, United Kingdom Department of Chemistry and Physics, Roger Williams University, 1 Old Ferry Road, Bristol, RI 02809, United States |
| Año: | 2013 |
| Volumen: | 52 |
| Número: | 6 |
| Página de inicio: | 2906 |
| Página de fin: | 2917 |
| DOI: | http://dx.doi.org/10.1021/ic302173g |
| Título revista: | Inorganic Chemistry |
| Título revista abreviado: | Inorg. Chem. |
| ISSN: | 00201669 |
| CODEN: | INOCA |
| Registro: | https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00201669_v52_n6_p2906_Pieslinger |
Referencias:
- Baraldo, L.M., Forlano, P., Parise, A.R., Slep, L.D., Olabe, J.A., (2001) Coord. Chem. Rev., 219, p. 881
- D'Alessandro, D.M., Keene, F.R., (2006) Chem. Rev., 106, p. 2270
- Dunbar, K.R., Heintz, R.A., (1997) Prog. Inorg. Chem., 45, p. 283
- Newton, G.N., Nihei, M., Oshio, H., (2011) Eur. J. Inorg. Chem., 2011, p. 3031
- Vahrenkamp, H., Geiss, A., Richardson, G.N., (1997) J. Chem. Soc., Dalton Trans., p. 3643
- Catala, L., Brinzei, D., Prado, Y., Gloter, A., Stephan, O., Rogez, G., Mallah, T., (2009) Angew. Chem., Int. Ed., 48, p. 183
- Culp, J.T., Park, J.-H., Frye, F., Huh, Y.-D., Meisel, M.W., Talham, D.R., (2005) Coord. Chem. Rev., 249, p. 2642
- Tanase, S., Reedijk, J., (2006) Coord. Chem. Rev., 250, p. 2501
- Ohba, M., Okawa, H., (2000) Coord. Chem. Rev., 198, p. 313
- Verdaguer, M., Bleuzen, A., Marvaud, V., Vaissermann, J., Seuleiman, M., Desplanches, C., Scuiller, A., Villain, F., (1999) Coord. Chem. Rev., 192, p. 1023
- Coe, B.J., Meyer, T.J., White, P.S., (1995) Inorg. Chem., 34, p. 3600
- Timpson, C.J., (1995), Ph.D. Dissertation, University of North Carolina, Chapel Hill, NC; Coe, B.J., Meyer, T.J., White, P.S., (1995) Inorg. Chem., 34, p. 593
- Albores, P., Slep, L.D., Weyhermuller, T., Baraldo, L.M., (2004) Inorg. Chem., 43, p. 6762
- Armarego, W.L.F., Perrin, D.D., (1996) Purification of Laboratory Chemicals, , 4 th ed. Butterworth-Heinemann: Oxford, U.K
- Nagao, H., Nishimura, H., Kitanaka, Y., Howell, F.S., Mukaida, M., Kakihana, H., (1990) Inorg. Chem., 29, p. 1693
- Noviandri, I., Brown, K.N., Fleming, D.S., Gulyas, P.T., Lay, P.A., Masters, A.F., Phillips, L., (1999) J. Phys. Chem. B, 103, p. 6713
- Kaim, W., Fiedler, J., (2009) Chem. Soc. Rev., 38, p. 3373
- (2006) SCALE3 ABSPACK: Empirical Absorption Correction, CrysAlis - Software Package, , Oxford Diffraction Ltd. Oxford, U.K
- Sheldrick, G.M., (1997) SHELXS97 and SHELXL97, Programs for Crystal Structure Resolution, , University of Göttingen: Göttingen, Germany
- Spek, A.L., (2009) Acta Crystallogr., Sect. D: Biol. Crystallogr., 65, p. 148
- Poddar, R.K., Agarwala, U., Manoharan, P., (1974) J. Inorg. Nucl. Chem., 36, p. 2275
- Siddiqui, S., Henderson, W.W., Shepherd, R.E., (1987) Inorg. Chem., 26, p. 3101
- Bendix, J., Steenberg, P., Søtofte, I., (2003) Inorg. Chem., 42, p. 4510
- Toma, L., Delgado, F., Ruizperez, C., Sletten, J., Cano, J., Clemente-Juan, J.M., Lloret, F., Julve, M., (2006) Coord. Chem. Rev., 250, p. 2176
- Laidlaw, W.M., Denning, R.G., (1994) J. Chem. Soc., Dalton Trans., pp. 1987-1994
- Sheng, T.L., Vahrenkamp, H., (2004) Eur. J. Inorg. Chem., 43, p. 1198
- Richardson, G.N., Brand, U., Vahrenkamp, H., (1999) Inorg. Chem., 38, p. 3070
- Geiss, A., Vahrenkamp, H., (1999) Eur. J. Inorg. Chem., p. 1793
- Roncaroli, F., Baraldo, L.M., Slep, L.D., Olabe, J.A., (2002) Inorg. Chem., 41, p. 1930
- Albores, P., Rossi, M.B., Baraldo, L.M., Slep, L.D., (2006) Inorg. Chem., 45, p. 10595
- Rossi, M.B., Abboud, K.A., Albores, P., Baraldo, L.M., (2010) Eur. J. Inorg. Chem., p. 5613
- Hush, N.S., (1967) Prog. Inorg. Chem., 8, p. 391
- Hush, N.S., (1968) Electrochim. Acta, 13, p. 1005
- Mulliken, R.S., (1952) J. Am. Chem. Soc., 74, p. 811
- Bignozzi, C.A., (1985) J. Am. Chem. Soc., p. 1644
- Bignozzi, C.A., Scandola, F., (1988) Inorg. Chem., p. 408
- Cutin, E.H., Katz, N.E., (1993) Polyhedron, 12, p. 955
- Scandola, F., Argazzi, R., Bignozzi, C.A., Chiorboli, C., Indelli, M.T., Rampi, M.A., (1993) Coord. Chem. Rev., 125, p. 283
- Watzky, M.A., MacAtangay, A.V., Vancamp, R.A., Mazzetto, S.E., Song, X.Q., Endicott, J.F., Buranda, T., (1997) J. Phys. Chem. A, 101, p. 8441
- MacAtangay, A.V., Endicott, J.F., (2000) Inorg. Chem., 39, p. 437
- Bublitz, G.U., Laidlaw, W.M., Denning, R.G., Boxer, S.G., (1998) J. Am. Chem. Soc., 120, p. 6068
- Brunschwig, B.S., Creutz, C., Sutin, N., (2002) Chem. Soc. Rev., 31, p. 168
- Rocha, R.C., Rein, F.N., Jude, H., Shreve, A.P., Concepcion, J.J., Meyer, T.J., (2008) Angew. Chem., Int. Ed., 47, p. 503
- De Candia, A.G., Singh, P., Kaim, W., Slep, L.D., (2009) Inorg. Chem., 48, p. 565
- Lin, J.-L., Tsai, C.-N., Huang, S.-Y., Endicott, J.F., Chen, Y.-J., Chen, H.-Y., (2011) Inorg. Chem., 50, p. 8274
- Robin, M.B., Day, P., (1967) Adv. Inorg. Chem. Radiochem., 10, p. 247
- Kettle, S.F.A., Diana, E., Boccaleri, E., Stanghellini, P.L., (2007) Inorg. Chem., 46, p. 2409
- Pfennig, B.W., Fritchman, V.A., Hayman, K.A., (2001) Inorg. Chem., 40, p. 255
- Concepcion, J.J., Dattelbaum, D.M., Meyer, T.J., Rocha, R.C., (2008) Philos. Trans. R. Soc., A, 366, p. 163
- D'Alessandro, D.M., Keene, F.R., (2006) Chem. Soc. Rev., 35, p. 424
Citas:
---------- APA ----------
Pieslinger, G.E., Albores, P., Slep, L.D., Coe, B.J., Timpson, C.J. & Baraldo, L.M. (2013) . Communication between remote moieties in linear Ru-Ru-Ru trimetallic cyanide-bridged complexes. Inorganic Chemistry, 52(6), 2906-2917.http://dx.doi.org/10.1021/ic302173g
---------- CHICAGO ----------
Pieslinger, G.E., Albores, P., Slep, L.D., Coe, B.J., Timpson, C.J., Baraldo, L.M. "Communication between remote moieties in linear Ru-Ru-Ru trimetallic cyanide-bridged complexes" . Inorganic Chemistry 52, no. 6 (2013) : 2906-2917.http://dx.doi.org/10.1021/ic302173g
---------- MLA ----------
Pieslinger, G.E., Albores, P., Slep, L.D., Coe, B.J., Timpson, C.J., Baraldo, L.M. "Communication between remote moieties in linear Ru-Ru-Ru trimetallic cyanide-bridged complexes" . Inorganic Chemistry, vol. 52, no. 6, 2013, pp. 2906-2917.http://dx.doi.org/10.1021/ic302173g
---------- VANCOUVER ----------
Pieslinger, G.E., Albores, P., Slep, L.D., Coe, B.J., Timpson, C.J., Baraldo, L.M. Communication between remote moieties in linear Ru-Ru-Ru trimetallic cyanide-bridged complexes. Inorg. Chem. 2013;52(6):2906-2917.http://dx.doi.org/10.1021/ic302173g
