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Abstract:

Free-volume integrals for hole theories of liquids were calculated for some special cases by Monte Carlo numerical integration. The dependence of the free volume on the number of nearest neighbors is thus obtained. Only molecules interacting with a Lennard-Jones potential and a temperature near the critical one have been considered. The results differ considerably from those of earlier theories, where spherical symmetry was assumed. However, the introduction of vacant cells (holes) does not improve the thermodynamic functions obtained with the cell theory of Lennard-Jones and Devonshire.

Registro:

Documento: Artículo
Título:Nonsphericalized free volumes for hole theories of liquids
Autor:Weissmann, M.
Filiación:Facultad de Ciencias Exactas y Naturales, Departamento de Meteorología, Peru 272, Buenos Aires, Argentina
Año:1964
Volumen:40
Número:1
Página de inicio:175
Página de fin:178
DOI: http://dx.doi.org/10.1063/1.1724856
Título revista:The Journal of Chemical Physics
ISSN:00219606
PDF:https://bibliotecadigital.exactas.uba.ar/download/paper/paper_00219606_v40_n1_p175_Weissmann.pdf
Registro:https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00219606_v40_n1_p175_Weissmann

Citas:

---------- APA ----------
(1964) . Nonsphericalized free volumes for hole theories of liquids. The Journal of Chemical Physics, 40(1), 175-178.
http://dx.doi.org/10.1063/1.1724856
---------- CHICAGO ----------
Weissmann, M. "Nonsphericalized free volumes for hole theories of liquids" . The Journal of Chemical Physics 40, no. 1 (1964) : 175-178.
http://dx.doi.org/10.1063/1.1724856
---------- MLA ----------
Weissmann, M. "Nonsphericalized free volumes for hole theories of liquids" . The Journal of Chemical Physics, vol. 40, no. 1, 1964, pp. 175-178.
http://dx.doi.org/10.1063/1.1724856
---------- VANCOUVER ----------
Weissmann, M. Nonsphericalized free volumes for hole theories of liquids. 1964;40(1):175-178.
http://dx.doi.org/10.1063/1.1724856