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Abstract:

The adherence of hematite (α-Fe2O3) particles onto mercury electrodes in water-ethanol mixtures has been studied by counting on optical microscope images, obtaining also the effective charge by electrophoretic measurements. The number of attached particles, when the ethanol content is small, decreases as the ethanol concentration increases. At an ethanol mole fraction near 0.2, the number of particles goes through a minimum and then increases with ethanol concentration. When the electrode potential is modified, curves of the number of particles vs ethanol mole fraction with the same shape are found, but they cross each other. The experimental behavior can be explained based on the dependence of particle/solution, metal/solution, and metal/particle interaction energies on the solvent composition.

Registro:

Documento: Artículo
Título:Adhesion of colloidal hematite onto mercury in water-ethanol media
Autor:Andrade, E.M.; Molina, F.V.; Posadas, D.
Filiación:INQUIMAE - Depto. de Quim. Inorg., Analítica y Quim. Fis., Universidad de Buenos Aires, 1428, Buenos Aires, Argentina
Departamento de Química, Facultad de Ciencias Exactas, Universidad de La Plata, Suc. 4, CC 16, 1900, La Plata, Argentina
Palabras clave:Adhesion; Hematite; Metal surface; Water-ethanol mixtures; alcohol; ferric oxide; mercury; solvent; water; adhesion; article; colloid; concentration response; electric potential; electrophoresis; microscopy; molecular interaction; priority journal; surface charge
Año:1999
Volumen:215
Número:2
Página de inicio:370
Página de fin:380
DOI: http://dx.doi.org/10.1006/jcis.1999.6243
Título revista:Journal of Colloid and Interface Science
Título revista abreviado:J. Colloid Interface Sci.
ISSN:00219797
CODEN:JCISA
CAS:alcohol, 64-17-5; ferric oxide, 1309-37-1, 56449-54-8; mercury, 14302-87-5, 7439-97-6; water, 7732-18-5
Registro:https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00219797_v215_n2_p370_Andrade

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Citas:

---------- APA ----------
Andrade, E.M., Molina, F.V. & Posadas, D. (1999) . Adhesion of colloidal hematite onto mercury in water-ethanol media. Journal of Colloid and Interface Science, 215(2), 370-380.
http://dx.doi.org/10.1006/jcis.1999.6243
---------- CHICAGO ----------
Andrade, E.M., Molina, F.V., Posadas, D. "Adhesion of colloidal hematite onto mercury in water-ethanol media" . Journal of Colloid and Interface Science 215, no. 2 (1999) : 370-380.
http://dx.doi.org/10.1006/jcis.1999.6243
---------- MLA ----------
Andrade, E.M., Molina, F.V., Posadas, D. "Adhesion of colloidal hematite onto mercury in water-ethanol media" . Journal of Colloid and Interface Science, vol. 215, no. 2, 1999, pp. 370-380.
http://dx.doi.org/10.1006/jcis.1999.6243
---------- VANCOUVER ----------
Andrade, E.M., Molina, F.V., Posadas, D. Adhesion of colloidal hematite onto mercury in water-ethanol media. J. Colloid Interface Sci. 1999;215(2):370-380.
http://dx.doi.org/10.1006/jcis.1999.6243