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Abstract:

The UV irradiation of aromatic alcohols leads to the formation of several products: carbonyl compounds, ethers, α-glycols and tetra-aryl-1,4-dioxanes. The photoformation of α-glycols is qualitatively and quantitatively compared to the photoreduction of the carbonyl compounds. It is noteworthy that the glycols are formed with a stereochemistry very different depending upon whether the substrate is an alcohol or a carbonyl compound. The structure, configuration and conformation of the 1-4-dixoanes obtained are studies as well as their origin. Other aspects of the photochemistry of the alcohols are analyzed using hydroperoxides as model substrates. © 1982.

Registro:

Documento: Artículo
Título:Photochemical reaction of alcohols-II. Irradiation of aromatic alcohols
Autor:Balsells, R.E.; Frasca, A.R.
Filiación:Departamento de Quimica Orgánica, Facultad de Ciencias Exactas y Naturales, Pabellón 2,3, Ciudad Universitaria, 1428-Buenos Aires, Argentina
Año:1982
Volumen:38
Número:16
Página de inicio:2525
Página de fin:2538
DOI: http://dx.doi.org/10.1016/0040-4020(82)85088-6
Título revista:Tetrahedron
Título revista abreviado:Tetrahedron
ISSN:00404020
CODEN:TETRA
Registro:https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00404020_v38_n16_p2525_Balsells

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Citas:

---------- APA ----------
Balsells, R.E. & Frasca, A.R. (1982) . Photochemical reaction of alcohols-II. Irradiation of aromatic alcohols. Tetrahedron, 38(16), 2525-2538.
http://dx.doi.org/10.1016/0040-4020(82)85088-6
---------- CHICAGO ----------
Balsells, R.E., Frasca, A.R. "Photochemical reaction of alcohols-II. Irradiation of aromatic alcohols" . Tetrahedron 38, no. 16 (1982) : 2525-2538.
http://dx.doi.org/10.1016/0040-4020(82)85088-6
---------- MLA ----------
Balsells, R.E., Frasca, A.R. "Photochemical reaction of alcohols-II. Irradiation of aromatic alcohols" . Tetrahedron, vol. 38, no. 16, 1982, pp. 2525-2538.
http://dx.doi.org/10.1016/0040-4020(82)85088-6
---------- VANCOUVER ----------
Balsells, R.E., Frasca, A.R. Photochemical reaction of alcohols-II. Irradiation of aromatic alcohols. Tetrahedron. 1982;38(16):2525-2538.
http://dx.doi.org/10.1016/0040-4020(82)85088-6