Artículo

La versión final de este artículo es de uso interno de la institución.
Consulte el artículo en la página del editor
Consulte la política de Acceso Abierto del editor

Abstract:

The study of Pb(II) binding to the system humic acid/goethite in acidic medium is reported in the present paper. From a macroscopic point of view, we have constructed the experimental sorption isotherms (using atomic absorption spectroscopy) and compared them with the prediction of the additivity rule. It is found that this system presents positive deviations, that is, the amount sorbed is about an order of magnitude higher than predicted. Apart from this, microscopic and structural aspects have also been studied using in situ and ex situ infrared spectroscopy. These results suggest that the presence of Pb(II) increases the amount of humic acid bound to the oxide. It is proposed that proton displacement due to the interaction between humic substances and the oxide, along with the formation of ternary complexes with the Pb(II) cation bridging the oxide and the humic substances (Type A complexes), cause the deviation from additivity. © 2006 Elsevier Ltd. All rights reserved.

Registro:

Documento: Artículo
Título:Binding of Pb(II) in the system humic acid/goethite at acidic pH
Autor:Orsetti, S.; de las Mercedes Quiroga, M.; Andrade, E.M.
Filiación:INQUIMAE, DQIAQF, Facultad de Ciencias Exactas y Naturales, Ciudad Universitaria Pabellon II, 1428 Buenos Aires, Argentina
Palabras clave:Metal pollution; Multisubstrate adsorption; Oxide-humate-metal complex; Soil Chemistry; Adsorption; Adsorption isotherms; Complexation; Infrared spectroscopy; Lead; Organic acids; Metal pollution; Multisubstrate adsorption; Oxide-humate-metal complex; Soil Chemistry; Soil pollution; cation; ferric hydroxide; humic acid; lead; oxide; proton; Adsorption; Adsorption isotherms; Complexation; Infrared spectroscopy; Lead; Organic acids; Soil pollution; goethite; humic acid; lead; oxide; pH; soil chemistry; soil pollution; sorption; acidity; article; atomic absorption spectrometry; comparative study; infrared spectroscopy; metal binding; pH; prediction; soil pollution; Humic Substances; Hydrogen-Ion Concentration; Iron Compounds; Lead; Spectrophotometry, Infrared; Spectrophotometry, Ultraviolet; Spectroscopy, Fourier Transform Infrared
Año:2006
Volumen:65
Número:11
Página de inicio:2313
Página de fin:2321
DOI: http://dx.doi.org/10.1016/j.chemosphere.2006.05.009
Título revista:Chemosphere
Título revista abreviado:Chemosphere
ISSN:00456535
CODEN:CMSHA
CAS:ferric hydroxide, 11113-66-9, 12022-37-6, 12181-28-1, 1309-33-7, 1310-14-1, 1317-60-8, 1317-63-1; humic acid, 1415-93-6; lead, 7439-92-1; oxide, 16833-27-5; proton, 12408-02-5, 12586-59-3; goethite, 1310-14-1; Humic Substances; Iron Compounds; Lead, 7439-92-1
Registro:https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00456535_v65_n11_p2313_Orsetti

Referencias:

  • Alcacio, T., Hesterberg, D., Chou, J., Martin, J., Beauchemin, S., Sayers, D., Molecular scale characteristics of Cu(II) bonding in goethite-humate complexes (2001) Geochim. Cosmochim. Acta, 65, pp. 1355-1366
  • Alvarez-Puebla, R.A., Valenzuela-Calahorro, C., Garrido, J.J., Retention of Co(II), Ni(II) and Cu(II) on a purified brown humic acid. Modeling and Characterization of the sorption process (2004) Langmuir, 20, pp. 3657-3664
  • Alvarez-Puebla, R.A., Valenzuela-Calahorro, C., Garrido, J.J., Cu(II) retention on a humic substance (2004) J. Colloid Interf. Sci., 270, pp. 47-55
  • Alvarez-Puebla, R.A., Garrido, J.J., Valenzuela-Calahorro, C., Goulet, P.J.G., Retention and induced aggregation of Co(II) on a humic substance: sorption isotherms, infrared absorption and molecular modeling (2005) Surf. Sci., 575, pp. 136-146
  • Arias, M., Barral, M.T., Mejuto, J.C., Enhancement of copper and cadmium adsorption on kaolin by the presence of humic acids (2002) Chemosphere, 48, pp. 1081-1088
  • Benedetti, M., Milne, C., Kinniburgh, D., Van Riemsdijk, W.H., Koopal, L., Metal ion binding to humic substances: application of the non-ideal competitive adsorption model (1995) Environ. Sci. Technol., 29, pp. 446-457
  • Bradl, H., Adsorption of heavy metal ions on soils and soils constituents (2004) J. Colloid Interf. Sci., 277, pp. 1-18
  • Dupuy, N., Douay, F., Infrared and chemometrics study of the interaction between heavy metals and organic matter in soils (2001) Spectrochim. Acta A, 57, pp. 1037-1047
  • Fu, H., Quan, X., Complexes of fulvic acid on the surface of hematite, goethite and akaganeite: FTIR observation (2005) Chemosphere, 63, pp. 403-410
  • Ghabbour, E.A., Shaker, M., El-Toukhy, A., Abid, I.M., Davies, G., Thermodynamics of metal cation binding by a solid-derived humic acid: binding of Fe(III), Pb(II) and Cu(II) (2005) Chemosphere, 63, pp. 477-483
  • Gustafsson, J., Modeling the acid-base properties and metal complexation of humic substances with the Stockholm humic model (2001) J. Colloid Interf. Sci., 244, pp. 102-112
  • Helmke, P.M., The chemical composition of soils (1999) Handbook of Soil Science, pp. B1-B24. , Sumner M.E. (Ed), CRC, Boca Raton
  • Hiemstra, T., Van Riemsdijk, W.H., A surface structural approach to ion adsorption: the charge distribution (CD) model (1996) J. Colloid Interf. Sci., 179, pp. 488-508
  • Hiemstra, T., Van Riemsdijk, W.H., On the relationship between surface structure and ion complexation of oxide-solution interfaces (2002) Encyclopedia of Surface and Colloid Science, pp. 3773-3792. , Hubbard A. (Ed), Marcel Dekker, Inc., New York
  • Jones, M., Bryan, N., Colloidal properties of humic substances (1998) Adv. Colloid Interf. Sci., 78, pp. 1-48
  • Kinniburgh, D.G., Milne, C., Benedetti, M., Pinheiro, J., Filius, J., Koopal, L., Van Riemsdijk, W.H., Metal ion binding by humic acid: application of the NICA Donnan model (1996) Environ. Sci. Technol., 30, pp. 1687-1698
  • Kinniburgh, D.G., Van Riemsdijk, W.H., Koopal, L., Borkovec, M., Benedetti, M., Avena, M., Ion binding to natural organic matter: competition, heterogeneity, stoichiometry and thermodynamic consistency (1999) Coll. Surf. A: Physicochem. Eng. Aspects, 151, pp. 147-166
  • Kovačević, D., Pohlmeier, A., Özbaş, G., Narres, H., Kallay, M., The adsorption of lead species on goethite (2000) Coll. Surf. A: Physicochem. Eng. Aspects, 166, pp. 225-233
  • Lawrence Roe, A., Hayes, K., Chisholm-Brause, C., Brown, J., Parks, G., Hodgson, K., Leckie, J., In situ X ray absorption study of lead ion surface complexes at the goethite-water interface (1991) Langmuir, 7, pp. 367-373
  • Lenhart, J.J., Honeyman, B.D., Uranium(VI) sorption to hematite in the presence of humic acid (1999) Geochim. Cosmochim. Acta, 63, pp. 2891-2901
  • Masset, S., Monteil-Rivera, F., Dupont, L., Dumonceau, J., Aplincourt, M., Influence of humic acid on sorption of Co(II), Sr(II) and Se(IV) on goethite (2000) Agronomie, 20, pp. 525-535
  • Milne, C.J., Kinniburgh, D.G., De Wit, J.C.M., Van Riemsdijk, W.H., Koopal, L.K., Analysis of proton binding by a peat humic acid using a simple electrostatic model (1995) Geochim. Cosmochim. Acta, 59, pp. 1101-1112
  • Murphy, R., Lenhart, J., Honeyman, B., The sorption of thorium (IV) and uranium (VI) to hematite in the presence of natural organic matter (1999) Coll. Surf. A: Physicochem. Eng. Aspects, 157, pp. 47-62
  • Ostergren, J., Trainor, T., Bargar, J., Brown, G., Parks, G., Inorganic ligand effects on Pb(II) sorption to goethite (α-FeOOH) I. Carbonate (2000) J. Colloid Interf. Sci., 225, pp. 466-482
  • Saito, T., Koopal, L.K., van Riemsdijk, W.H., Nagasaki, S., Tanaka, S., Adsorption of humic acid on goethite: isotherms, charge adjustments, and potential profiles (2004) Langmuir, 20, pp. 689-700
  • Saito, T., Koopal, L.K., Nagasaki, S., Tanaka, S., Analysis of copper binding in the ternary system Cu2+/humic acid/goethite at neutral to acidic pH (2005) Environ. Sci.Technol., 39, pp. 4886-4893
  • Schwertmann, U., Cornell, R., (1991) Iron Oxides in the Laboratory, , VCH, New York (Chapter 5)
  • Smith, E., Rey-Castro, C., Longworth, H., Lofts, S., Lawlor, A., Tipping, E., Cation binding by acid-washed peat, interpreted with humic ion-binding model VI FD (2004) Eur. J. Soil Sci., 55, pp. 433-447
  • Spark, K.M., Wells, J.D., Johnson, B.B., Characteristics of the sorption of humic acid by soil minerals (1997) Aust. J. Soil Res., 35, pp. 103-112
  • Sparks, D.L., (1995) Environmental Soil Chemistry, , Academic Press, San Diego, CA, USA
  • Sposito, G., (1984) The Surface Chemistry of Soils, , Oxford University Press, New York (Chapter 3)
  • Swift, R.S., Organic matter characterization (1996) Methods of Soil Analysis. Part 3: Chemical Methods, pp. 1011-1070. , Sparks D.L. (Ed), Soil Science Society of America, Madison, WI
  • Tejedor-Tejedor, M.I., Anderson, M., In situ attenuated total reflection Fourier transform infrared Studies of the goethite (a-FeOOH)-aqueous solution interface (1986) Langmuir, 2, pp. 203-210
  • Tipping, E., Hurley, M., A unifying model of cation binding by humic substances (1992) Geochim. Cosmochim. Acta, 56, pp. 3627-3641
  • Varadachari, C., Chattopadhyay, T., Ghosh, K., Complexation of humic substances with oxides of iron and aluminum (1997) Soil Sci., 162, pp. 28-34
  • Varadachari, C., Chattopadhyay, T., Ghosh, K., The crystallo-chemistry of oxide-humus complexes (2000) Aust. J. Soil Res., 38, pp. 789-806
  • Vermeer, A.W.P., Mcculloch, J.K., van Riemsdijk, W., Koopal, L.K., Metal ion adsorption to complexes of humic acid and metal oxides: deviations from the additivity rule (1999) Environ. Sci. Technol., 33, pp. 3892-3897
  • Weng, L.P., Koopal, L., Hiemstra, T., Meeussen, J., Van Riemsdijk, W.H., Interactions of calcium and fulvic acid at the goethite-water interface (2005) Geochim. Cosmochim. Acta, 69, pp. 325-339
  • Wu, Z., Gu, Z., Wang, X., Evans, L., Guo, H., Effects of organic acids on adsorption of lead onto montmorillonite, goethite and humic acid (2003) Environ. Pollut., 121, pp. 469-475
  • Zachara, J., Westall, J., Chemical modeling of ion adsorption in soils (1999) Soil Physical Chemistry, pp. 47-96. , Sparks D.L. (Ed), CRC Press

Citas:

---------- APA ----------
Orsetti, S., de las Mercedes Quiroga, M. & Andrade, E.M. (2006) . Binding of Pb(II) in the system humic acid/goethite at acidic pH. Chemosphere, 65(11), 2313-2321.
http://dx.doi.org/10.1016/j.chemosphere.2006.05.009
---------- CHICAGO ----------
Orsetti, S., de las Mercedes Quiroga, M., Andrade, E.M. "Binding of Pb(II) in the system humic acid/goethite at acidic pH" . Chemosphere 65, no. 11 (2006) : 2313-2321.
http://dx.doi.org/10.1016/j.chemosphere.2006.05.009
---------- MLA ----------
Orsetti, S., de las Mercedes Quiroga, M., Andrade, E.M. "Binding of Pb(II) in the system humic acid/goethite at acidic pH" . Chemosphere, vol. 65, no. 11, 2006, pp. 2313-2321.
http://dx.doi.org/10.1016/j.chemosphere.2006.05.009
---------- VANCOUVER ----------
Orsetti, S., de las Mercedes Quiroga, M., Andrade, E.M. Binding of Pb(II) in the system humic acid/goethite at acidic pH. Chemosphere. 2006;65(11):2313-2321.
http://dx.doi.org/10.1016/j.chemosphere.2006.05.009