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Abstract:

Various O-acyl derivatives of 2-mercaptoethanol have been obtained enzymatically by lipase-catalyzed chemospecific esterification reactions of the substrate and several aliphatic carboxylic acid ethyl esters. © 1994 Kluwer Academic Publishers.

Registro:

Documento: Artículo
Título:An improved procedure for chemospecific acylation of 2-mercaptoethanol by lipase-catalyzed transesterification
Autor:Baldessari, A.; Iglesias, L.E.; Gros, E.G.
Filiación:Departamento de Química Orgánica, Facultad de Ciencias Exactas y Naturales, Universidad de Buenos Aires, Pabellón 2, Ciudad Universitaria, Buenos Aires, 1428, Argentina
Palabras clave:aliphatic carboxylic acid; ester; mercaptoethanol; solvent; triacylglycerol lipase; acylation; article; catalysis; chemical reaction; esterification; temperature
Año:1994
Volumen:16
Número:5
Página de inicio:479
Página de fin:484
DOI: http://dx.doi.org/10.1007/BF01023329
Título revista:Biotechnology Letters
Título revista abreviado:Biotechnol Lett
ISSN:01415492
CODEN:BILED
Registro:https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_01415492_v16_n5_p479_Baldessari

Referencias:

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  • Baldessari, A., Iglesias, L. E. and Gros, E. G. (1992). J. Chem. Res. (S), 204–205; Baldessari, A., Iglesias, L. E. and Gros, E. G. (1993), J. Chem. Res. (S), 382–383; Colombo, D., Ronchetti, F., Scala, A., Toma, L., Enzymic Acylation of Methyl D- and L-Glucopyranosides and 6-Deoxy-glucopyranosides (1992) Journal of Carbohydrate Chemistry, 11, pp. 89-94
  • Chen, C.S., Sih, C.J., General Aspects and Optimization of Enantioselective Biocatalysis in Organic Solvents: The Use of Lipases[New Synthetic Methods(76)] (1989) Angewandte Chemie International Edition in English, 28, pp. 695-707
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Citas:

---------- APA ----------
Baldessari, A., Iglesias, L.E. & Gros, E.G. (1994) . An improved procedure for chemospecific acylation of 2-mercaptoethanol by lipase-catalyzed transesterification. Biotechnology Letters, 16(5), 479-484.
http://dx.doi.org/10.1007/BF01023329
---------- CHICAGO ----------
Baldessari, A., Iglesias, L.E., Gros, E.G. "An improved procedure for chemospecific acylation of 2-mercaptoethanol by lipase-catalyzed transesterification" . Biotechnology Letters 16, no. 5 (1994) : 479-484.
http://dx.doi.org/10.1007/BF01023329
---------- MLA ----------
Baldessari, A., Iglesias, L.E., Gros, E.G. "An improved procedure for chemospecific acylation of 2-mercaptoethanol by lipase-catalyzed transesterification" . Biotechnology Letters, vol. 16, no. 5, 1994, pp. 479-484.
http://dx.doi.org/10.1007/BF01023329
---------- VANCOUVER ----------
Baldessari, A., Iglesias, L.E., Gros, E.G. An improved procedure for chemospecific acylation of 2-mercaptoethanol by lipase-catalyzed transesterification. Biotechnol Lett. 1994;16(5):479-484.
http://dx.doi.org/10.1007/BF01023329