Abstract:
In this work we present the use of EMFAAS (Electrothermal Metallic Furnace Atomic Absorption Spectroscopy) for the determination of Cd in the tobacco cigarettes of five commercial brands. Optimization of the experimental conditions was done by controlling the sample flow rate and the temperature of both the injection capillary and the atomization cell. The determination was made in the whole cigarettes, filters and ashes of the cigarettes once consumed, cases in which the Cd concentration is much lower and its quantification is more difficult. For the validation of the results, the ICP-OES technique was used, obtaining good agreement within the experimental error. The results show that EMFAAS is a promising tool for the determination of volatile analytes. © 2018 The Royal Society of Chemistry.
Registro:
Documento: |
Artículo
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Título: | Determination of cadmium in commercial tobacco by EMFAAS |
Autor: | Carrone, G.; Morzan, E.; Tudino, M.; Etchenique, R. |
Filiación: | Departamento de Química Inorganica, Analítica y Química Física, INQUIMAE, Facultad de Ciencias Exactas y Naturales, Universidad de Buenos Aires Ciudad Universitaria, Pabellón 2, Buenos Aires, AR1428EHA, Argentina
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Palabras clave: | Absorption spectroscopy; Cadmium; Analytes; Atomic absorption spectroscopy; Cd concentrations; Experimental conditions; Experimental errors; ICP-OES; Tobacco |
Año: | 2018
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Volumen: | 33
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Número: | 11
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Página de inicio: | 1970
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Página de fin: | 1973
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DOI: |
http://dx.doi.org/10.1039/c8ja00195b |
Título revista: | Journal of Analytical Atomic Spectrometry
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Título revista abreviado: | J Anal At Spectrom
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ISSN: | 02679477
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CODEN: | JASPE
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Registro: | https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_02679477_v33_n11_p1970_Carrone |
Referencias:
- Walsh, A., (1955) Spectrochim. Acta, 7, p. 108
- Ĺvov, B.V., (1969) Spectrochim. Acta, Part B, 24 (1), p. 53
- Sturgeon, R., (1996) Fresenius' J. Anal. Chem., 355 (56), p. 425
- Hieftje, G., (1990) Fresenius' J. Anal. Chem., 337 (5), p. 528
- Holcombe, J.A., Borges, D.L., Graphite Furnace Atomic Absorption Spectrometry (2010) Encyclopedia of Analytical Chemistry
- Gaspar, A., Berndt, H., (2000) Anal. Chem., 72, p. 240
- Morzan, E., Carrone, G., Tudino, M., Etchenique, R., (2017) Anal. Methods, 9, p. 756
- Ellis, K.J., Vartsky, D., Zanzi, I., Cohn, S.H., Yasumura, S., (1979) Science, 205, p. 323
- Borges, D.L.G., Silva Da Veiga, M.A.M., Azzolin Frescura, V.L., Welz, B., Curtius, A.J., (2003) J. Anal. At. Spectrom., 18, p. 501
- Friberg, L., (1985) Cadmium and Health: A Toxicological and Epidemiological Appraisal, , CRC Press, Boca Raton, FL
- Satarug, S., Moore, M.R., (2004) Environ. Health Perspect., 112, p. 1099
- Mench, M., Martin, E., (1991) Plant Soil, 32, p. 187
- Robinson, J.W., Kevan, L.J., (1963) Anal. Chim. Acta, 28, p. 170
- Ross, R.T., Gonzalez, J.G., (1974) Anal. Chim. Acta, 70, p. 443
- Zhang, D., Li, C., Yang, L., Sun, H., (1998) J. Anal. At. Spectrom., 13, p. 1155
- Chen, J., Teo, K.C., (2001) Anal. Chim. Acta, 450, p. 215
- Muñoz, J., Baena, J.R., Gallego, M., Valcarcel, M., (2002) J. Anal. At. Spectrom., 17, p. 716
- Ferreira, S.L., De Andrade, J.B., Maria Das Graças, A.K., Pereira, M.D.G., Lemos, V.A., Dos Santos, W.N., Medeiros Rodrigues, F., Da Silva, E.G., (2007) J. Hazard. Mater., 145, p. 358
- Lopez-Garcia, I., Vicente-Martinez, Y., Hernandez-Cordoba, M., (2015) J. Anal. At. Spectrom., 30, p. 375
Citas:
---------- APA ----------
Carrone, G., Morzan, E., Tudino, M. & Etchenique, R.
(2018)
. Determination of cadmium in commercial tobacco by EMFAAS. Journal of Analytical Atomic Spectrometry, 33(11), 1970-1973.
http://dx.doi.org/10.1039/c8ja00195b---------- CHICAGO ----------
Carrone, G., Morzan, E., Tudino, M., Etchenique, R.
"Determination of cadmium in commercial tobacco by EMFAAS"
. Journal of Analytical Atomic Spectrometry 33, no. 11
(2018) : 1970-1973.
http://dx.doi.org/10.1039/c8ja00195b---------- MLA ----------
Carrone, G., Morzan, E., Tudino, M., Etchenique, R.
"Determination of cadmium in commercial tobacco by EMFAAS"
. Journal of Analytical Atomic Spectrometry, vol. 33, no. 11, 2018, pp. 1970-1973.
http://dx.doi.org/10.1039/c8ja00195b---------- VANCOUVER ----------
Carrone, G., Morzan, E., Tudino, M., Etchenique, R. Determination of cadmium in commercial tobacco by EMFAAS. J Anal At Spectrom. 2018;33(11):1970-1973.
http://dx.doi.org/10.1039/c8ja00195b