Artículo
Corti, H.R. "Thermodynamic properties of concentrated heteroionic polyelectrolyte solutions" (1987) Journal of the Chemical Society, Faraday Transactions 1: Physical Chemistry in Condensed Phases. 83(11):3249-3258
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Abstract:
The water sorption isotherms of concentrated sodium-caesium polystyrene sulphonate solutions have been measured as a function of the ionic composition at 298.15 K. Also the densities of the solid-like solutions are reported at various water contents. The systems obey the B.E.T. isotherm only over a limited range of concentration, but empirical equations have been found which describe the behaviour of the linear and crosslinked ion-exchangers over the concentration range of practical interest. The heteroionic systems studied here are far from ideal behaviour; anomalies are found in the sodium-rich region, probably caused by a lattice-like structure involving caesium ions.
Registro:
| Documento: | Artículo |
| Título: | Thermodynamic properties of concentrated heteroionic polyelectrolyte solutions |
| Autor: | Corti, H.R. |
| Filiación: | Departamento de Química Inorgánica, Analítica y Química Física, Universidad de Buenos Aires, Ciudad Universitaria, Nuñez, Argentina |
| Año: | 1987 |
| Volumen: | 83 |
| Número: | 11 |
| Página de inicio: | 3249 |
| Página de fin: | 3258 |
| DOI: | http://dx.doi.org/10.1039/F19878303249 |
| Título revista: | Journal of the Chemical Society, Faraday Transactions 1: Physical Chemistry in Condensed Phases |
| ISSN: | 03009599 |
| Registro: | https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_03009599_v83_n11_p3249_Corti |
Referencias:
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Citas:
---------- APA ----------
(1987) . Thermodynamic properties of concentrated heteroionic polyelectrolyte solutions. Journal of the Chemical Society, Faraday Transactions 1: Physical Chemistry in Condensed Phases, 83(11), 3249-3258.http://dx.doi.org/10.1039/F19878303249
---------- CHICAGO ----------
Corti, H.R. "Thermodynamic properties of concentrated heteroionic polyelectrolyte solutions" . Journal of the Chemical Society, Faraday Transactions 1: Physical Chemistry in Condensed Phases 83, no. 11 (1987) : 3249-3258.http://dx.doi.org/10.1039/F19878303249
---------- MLA ----------
Corti, H.R. "Thermodynamic properties of concentrated heteroionic polyelectrolyte solutions" . Journal of the Chemical Society, Faraday Transactions 1: Physical Chemistry in Condensed Phases, vol. 83, no. 11, 1987, pp. 3249-3258.http://dx.doi.org/10.1039/F19878303249
---------- VANCOUVER ----------
Corti, H.R. Thermodynamic properties of concentrated heteroionic polyelectrolyte solutions. 1987;83(11):3249-3258.http://dx.doi.org/10.1039/F19878303249
