Artículo

Moreno, M.; Baronetti, G.T.; Laborde, M.A.; Mariño, F.J. "Kinetics of preferential CO oxidation in H2 excess (COPROX) over CuO/CeO2 catalysts" (2008) International Journal of Hydrogen Energy. 33(13):3538-3542
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Abstract:

A kinetic study has been performed for CO oxidation in hydrogen excess, i.e. under COPROX conditions, over CuO/CeO2 catalysts. Experiences under differential and integral reactor conditions have been made and a simple power-law type mathematical expression was obtained. The fitted parameters were activation energy (55 kJ mol-1) and partial orders of reaction (very close to 0 for O2 and 0.72 for CO). These results are consistent with mechanisms proposed in the literature for CO oxidation reaction. © 2008 International Association for Hydrogen Energy.

Registro:

Documento: Artículo
Título:Kinetics of preferential CO oxidation in H2 excess (COPROX) over CuO/CeO2 catalysts
Autor:Moreno, M.; Baronetti, G.T.; Laborde, M.A.; Mariño, F.J.
Filiación:Laboratorio de Procesos Catalíticos, DIQ-FI, Universidad de Buenos Aires, Pabellon Industrias, Ciudad Universitaria, 1428 Buenos Aires, Argentina
Palabras clave:Cerium; CO preferential oxidation; Copper; Hydrogen; Kinetics; PEMFC; Hydrogen; Oxidation; (I ,J) conditions; CO-oxidation; Kinetic studies; Preferential CO oxidation (PROX); Chemical oxygen demand
Año:2008
Volumen:33
Número:13
Página de inicio:3538
Página de fin:3542
DOI: http://dx.doi.org/10.1016/j.ijhydene.2008.03.043
Título revista:International Journal of Hydrogen Energy
Título revista abreviado:Int J Hydrogen Energy
ISSN:03603199
CODEN:IJHED
Registro:https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_03603199_v33_n13_p3538_Moreno

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Citas:

---------- APA ----------
Moreno, M., Baronetti, G.T., Laborde, M.A. & Mariño, F.J. (2008) . Kinetics of preferential CO oxidation in H2 excess (COPROX) over CuO/CeO2 catalysts. International Journal of Hydrogen Energy, 33(13), 3538-3542.
http://dx.doi.org/10.1016/j.ijhydene.2008.03.043
---------- CHICAGO ----------
Moreno, M., Baronetti, G.T., Laborde, M.A., Mariño, F.J. "Kinetics of preferential CO oxidation in H2 excess (COPROX) over CuO/CeO2 catalysts" . International Journal of Hydrogen Energy 33, no. 13 (2008) : 3538-3542.
http://dx.doi.org/10.1016/j.ijhydene.2008.03.043
---------- MLA ----------
Moreno, M., Baronetti, G.T., Laborde, M.A., Mariño, F.J. "Kinetics of preferential CO oxidation in H2 excess (COPROX) over CuO/CeO2 catalysts" . International Journal of Hydrogen Energy, vol. 33, no. 13, 2008, pp. 3538-3542.
http://dx.doi.org/10.1016/j.ijhydene.2008.03.043
---------- VANCOUVER ----------
Moreno, M., Baronetti, G.T., Laborde, M.A., Mariño, F.J. Kinetics of preferential CO oxidation in H2 excess (COPROX) over CuO/CeO2 catalysts. Int J Hydrogen Energy. 2008;33(13):3538-3542.
http://dx.doi.org/10.1016/j.ijhydene.2008.03.043