Artículo
Tomasini, E.P.; Halac, E.B.; Reinoso, M.; Di Liscia, E.J.; Maier, M.S. "Micro-Raman spectroscopy of carbon-based black pigments" (2012) Journal of Raman Spectroscopy. 43(11):1671-1675
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Abstract:
Carbon-based black pigments are a wide group of dark-colored materials, which are classified according to the starting material used and their method of manufacture. Raman spectroscopy is an ideal technique for the characterization of carbonaceous matter: crystalline carbon materials present well-defined peaks, which can be easily assigned; amorphous carbon materials, on the other hand, show broad bands between 1300 and 1600 cm -1. The aim of this work was the discrimination between carbon-based pigments by micro-Raman spectroscopy. Five carbon-based pigments provided by Zecchi (lampblack, ivory black, bistre, bitumen, and graphite), two humic-earth materials [Van Dyck (Kremer) and Earth of Kassel (Zecchi)], and a commercial wood charcoal were studied. Raman spectra of all the samples showed the characteristic bands at approximately 1580 and 1350 cm -1; however, a clear difference in position, width, and relative intensity could be observed for most of the samples. The resulting analysis showed that micro-Raman spectroscopy allowed the discrimination of most of the reference pigments and allowed the identification of carbon-based black pigments in two South American colonial paintings dated from the early 18th century. Copyright © 2012 John Wiley & Sons, Ltd.
Registro:
| Documento: | Artículo |
| Título: | Micro-Raman spectroscopy of carbon-based black pigments |
| Autor: | Tomasini, E.P.; Halac, E.B.; Reinoso, M.; Di Liscia, E.J.; Maier, M.S. |
| Filiación: | UMYMFOR, Departamento de Química Orgánica, Ciudad Universitaria (C1428EGA), Pabellõn 2, Ciudad Autõnoma de Buenos Aires, Argentina Gerencia de Investigaciõn y Aplicaciones, Comisiõn Nacional de Energía Atõmica Villa Martelli, Av. General Paz 1499 (B1650KNA), Buenos Aires, Argentina Escuela de Ciencia y Tecnología, Universidad Nacional de San Martín San Martín, M. de Irigoyen 3100 (B1650KNA), Buenos Aires, Argentina |
| Palabras clave: | art and archaeology; carbon-based pigments; colonial art; micro-Raman spectroscopy |
| Año: | 2012 |
| Volumen: | 43 |
| Número: | 11 |
| Página de inicio: | 1671 |
| Página de fin: | 1675 |
| DOI: | http://dx.doi.org/10.1002/jrs.4159 |
| Título revista: | Journal of Raman Spectroscopy |
| Título revista abreviado: | J. Raman Spectrosc. |
| ISSN: | 03770486 |
| CODEN: | JRSPA |
| Registro: | https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_03770486_v43_n11_p1671_Tomasini |
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Citas:
---------- APA ----------
Tomasini, E.P., Halac, E.B., Reinoso, M., Di Liscia, E.J. & Maier, M.S. (2012) . Micro-Raman spectroscopy of carbon-based black pigments. Journal of Raman Spectroscopy, 43(11), 1671-1675.http://dx.doi.org/10.1002/jrs.4159
---------- CHICAGO ----------
Tomasini, E.P., Halac, E.B., Reinoso, M., Di Liscia, E.J., Maier, M.S. "Micro-Raman spectroscopy of carbon-based black pigments" . Journal of Raman Spectroscopy 43, no. 11 (2012) : 1671-1675.http://dx.doi.org/10.1002/jrs.4159
---------- MLA ----------
Tomasini, E.P., Halac, E.B., Reinoso, M., Di Liscia, E.J., Maier, M.S. "Micro-Raman spectroscopy of carbon-based black pigments" . Journal of Raman Spectroscopy, vol. 43, no. 11, 2012, pp. 1671-1675.http://dx.doi.org/10.1002/jrs.4159
---------- VANCOUVER ----------
Tomasini, E.P., Halac, E.B., Reinoso, M., Di Liscia, E.J., Maier, M.S. Micro-Raman spectroscopy of carbon-based black pigments. J. Raman Spectrosc. 2012;43(11):1671-1675.http://dx.doi.org/10.1002/jrs.4159
