Artículo

Díaz Pace, D.M.; Miguel, R.E.; Di Rocco, H.O.; Anabitarte García, F.; Pardini, L.; Legnaioli, S.; Lorenzetti, G.; Palleschi, V. "Quantitative analysis of metals in waste foundry sands by calibration free-laser induced breakdown spectroscopy" (2017) Spectrochimica Acta - Part B Atomic Spectroscopy. 131:58-65
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Abstract:

Laser-induced breakdown spectroscopy (LIBS) was applied for quantitative analysis of the elemental composition of waste molding and core sands produced from industry as part of the casting process. To perform the analysis, waste foundry sands (WFS) were collected from metalcasting foundries and prepared in the form of solid pellets with the addition of polyvinyl alcohol as binder. The measurements were carried out using the Mobile double pulse instrument for LIBS analysis (Modì). The spectral analysis was carried out with the calibration-free approach (CF-LIBS). Metal elements commonly found in WFS including Al, Ba, Fe, Li, Mg, Mn, Pb, Ti, Zr, and Zn, were detected and quantified. The metal concentrations for WFS were compared with virgin sand to assess the influence of the casting material as well as the binders used in the foundries to reclaim the sands. The results demonstrated the feasibility of LIBS method as an alternative or complementary technique for the chemical characterization of WFS. © 2017 Elsevier B.V.

Registro:

Documento: Artículo
Título:Quantitative analysis of metals in waste foundry sands by calibration free-laser induced breakdown spectroscopy
Autor:Díaz Pace, D.M.; Miguel, R.E.; Di Rocco, H.O.; Anabitarte García, F.; Pardini, L.; Legnaioli, S.; Lorenzetti, G.; Palleschi, V.
Filiación:Centro de Investigaciones en Física e Ingeniería del Centro de la Provincia de Buenos Aires (CIFICEN), CONICET, CICPBA, Fac. Cs. Exactas UNCPBA, Campus Universitario, (B7000GHG) Tandil, Buenos Aires, Argentina
National Institute of Agricultural Technology, EEA INTA Chilecito, Ruta de la Producción Km 7,5 (5360) Tilimuqui, Chilecito, La Rioja, Argentina
Photonic Engineering Group, Universidad de Cantabria, Edificio I + D + iTelecomunicación, Dpto. TEISA, Santander, 39005, Spain
Institute of Chemistry of Organometallic Compounds, Research Area of National Research Council, Via G. Moruzzi, 1, Pisa, 56124, Italy
Palabras clave:Laser-induced breakdown spectroscopy; LIBS; Plasma characterization; Waste sand; Atomic emission spectroscopy; Binders; Bins; Calibration; Chemical analysis; Foundries; Foundry sand; Laser induced breakdown spectroscopy; Magnesium; Manganese; Metal analysis; Metals; Sand; Titanium; Chemical characterization; Complementary techniques; Elemental compositions; Laserinduced breakdown spectroscopy (LIBS); LIBS; Metal concentrations; Plasma characterization; Waste sands; Spectrum analysis
Año:2017
Volumen:131
Página de inicio:58
Página de fin:65
DOI: http://dx.doi.org/10.1016/j.sab.2017.03.007
Título revista:Spectrochimica Acta - Part B Atomic Spectroscopy
Título revista abreviado:Spectrochim. Acta Part B At. Spectrosc.
ISSN:05848547
CODEN:SAASB
Registro:https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_05848547_v131_n_p58_DiazPace

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Citas:

---------- APA ----------
Díaz Pace, D.M., Miguel, R.E., Di Rocco, H.O., Anabitarte García, F., Pardini, L., Legnaioli, S., Lorenzetti, G.,..., Palleschi, V. (2017) . Quantitative analysis of metals in waste foundry sands by calibration free-laser induced breakdown spectroscopy. Spectrochimica Acta - Part B Atomic Spectroscopy, 131, 58-65.
http://dx.doi.org/10.1016/j.sab.2017.03.007
---------- CHICAGO ----------
Díaz Pace, D.M., Miguel, R.E., Di Rocco, H.O., Anabitarte García, F., Pardini, L., Legnaioli, S., et al. "Quantitative analysis of metals in waste foundry sands by calibration free-laser induced breakdown spectroscopy" . Spectrochimica Acta - Part B Atomic Spectroscopy 131 (2017) : 58-65.
http://dx.doi.org/10.1016/j.sab.2017.03.007
---------- MLA ----------
Díaz Pace, D.M., Miguel, R.E., Di Rocco, H.O., Anabitarte García, F., Pardini, L., Legnaioli, S., et al. "Quantitative analysis of metals in waste foundry sands by calibration free-laser induced breakdown spectroscopy" . Spectrochimica Acta - Part B Atomic Spectroscopy, vol. 131, 2017, pp. 58-65.
http://dx.doi.org/10.1016/j.sab.2017.03.007
---------- VANCOUVER ----------
Díaz Pace, D.M., Miguel, R.E., Di Rocco, H.O., Anabitarte García, F., Pardini, L., Legnaioli, S., et al. Quantitative analysis of metals in waste foundry sands by calibration free-laser induced breakdown spectroscopy. Spectrochim. Acta Part B At. Spectrosc. 2017;131:58-65.
http://dx.doi.org/10.1016/j.sab.2017.03.007