Artículo

Menendez, R.B.; Graschinsky, C.; Amadeo, N.E. "Sorption-enhanced ethanol steam reforming process in a fixed-bed reactor" (2018) Industrial and Engineering Chemistry Research. 57(34):11547-11553
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Abstract:

Sorption-enhanced ethanol steam reforming is an alternative to nonrenewable sources to produce high purity hydrogen by simplifying the purification train required to obtain cell grade hydrogen. In this work, NiMgAl hydrotalcite was used as a catalyst precursor and CaO as a sorbent. The catalyst-sorbent configuration in the fixed-bed reactor, the effect of the sorbent/catalyst mass ratio, and the reaction temperature were the focus of our study. It was found that the well-mixed catalyst and sorbent configuration resulted in the highest hydrogen purity in the prebreakthrough period and the lowest CO concentration. Besides, it was possible to produce high purity hydrogen (>95%) at 723 K with a hydrogen yield equal to that obtained at 873 K without sorbent. Finally, it was corroborated that after 20 reaction/regeneration cycles the CO concentration was still lower than that obtained at the WGS reactor exit. © 2018 American Chemical Society.

Registro:

Documento: Artículo
Título:Sorption-enhanced ethanol steam reforming process in a fixed-bed reactor
Autor:Menendez, R.B.; Graschinsky, C.; Amadeo, N.E.
Filiación:Instituto de Tecnologías del Hidrógeno y Energías Sostenibles (ITHES), UBA - CONICET, Pabellón de Industrias, Ciudad Universitaria, Avenida Intendente Güiraldes 2160, Caba, 1428, Argentina
Palabras clave:Catalysts; Chemical reactors; Ethanol; Hydrogen production; Sorbents; Sorption; Ternary alloys; Breakthrough periods; Catalyst precursors; CO concentrations; Ethanol steam reforming; Fixed bed reactor; Hydrogen yields; Non-renewable; Reaction temperature; Steam reforming
Año:2018
Volumen:57
Número:34
Página de inicio:11547
Página de fin:11553
DOI: http://dx.doi.org/10.1021/acs.iecr.8b01657
Título revista:Industrial and Engineering Chemistry Research
Título revista abreviado:Ind. Eng. Chem. Res.
ISSN:08885885
CODEN:IECRE
Registro:https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_08885885_v57_n34_p11547_Menendez

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Citas:

---------- APA ----------
Menendez, R.B., Graschinsky, C. & Amadeo, N.E. (2018) . Sorption-enhanced ethanol steam reforming process in a fixed-bed reactor. Industrial and Engineering Chemistry Research, 57(34), 11547-11553.
http://dx.doi.org/10.1021/acs.iecr.8b01657
---------- CHICAGO ----------
Menendez, R.B., Graschinsky, C., Amadeo, N.E. "Sorption-enhanced ethanol steam reforming process in a fixed-bed reactor" . Industrial and Engineering Chemistry Research 57, no. 34 (2018) : 11547-11553.
http://dx.doi.org/10.1021/acs.iecr.8b01657
---------- MLA ----------
Menendez, R.B., Graschinsky, C., Amadeo, N.E. "Sorption-enhanced ethanol steam reforming process in a fixed-bed reactor" . Industrial and Engineering Chemistry Research, vol. 57, no. 34, 2018, pp. 11547-11553.
http://dx.doi.org/10.1021/acs.iecr.8b01657
---------- VANCOUVER ----------
Menendez, R.B., Graschinsky, C., Amadeo, N.E. Sorption-enhanced ethanol steam reforming process in a fixed-bed reactor. Ind. Eng. Chem. Res. 2018;57(34):11547-11553.
http://dx.doi.org/10.1021/acs.iecr.8b01657