Artículo
Dos Santos Afonso, M.; Czarnowski, J. "Kinetics and Mechanism of the Thermal Reaction between Trifluoromethylhypofluorite and 1,1-Dichlorodifluoroethylene" (1988) Zeitschrift fur Physikalische Chemie. 158(Part_1):25-34
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Abstract:
The thermal addition of CF3OF to CF2CC12 has been studied between -7.0 and 29.7 °C. The pressure of CF3OF was varied between 6.4 and 196.7 Torr and that of CF2CC12 between 5.4 and 203 Torr. CF3CC12F, CF3o(CF2CC12)F and CF3o(CF2CCl2)1oCF3, where i = 2,3 … n, were the products. Above 110 Torr of olefin, non-volatile condensate appeared. © by R. Oldenbourg Verlag
Registro:
| Documento: | Artículo |
| Título: | Kinetics and Mechanism of the Thermal Reaction between Trifluoromethylhypofluorite and 1,1-Dichlorodifluoroethylene |
| Autor: | Dos Santos Afonso, M.; Czarnowski, J. |
| Filiación: | Departamento de Quimica Inorganica, Analitica y Quimica Fisica, Facultad de Ciencias Exactas y Naturales, Universitaria, Pabellon II, UBA, Intendente Giiiraldes 2620, Nunez (1428), Buenos Aires, Argentina Instituto de Investigaciones Fisicoquimicas Teoricas y Aplicadas (INIFTA), Casilla de Correo 16, Sucursal 4, 1900 La Plata, Argentina |
| Palabras clave: | 1,1-Dichlorodifluoroethylene, reaction with trifluoromethylhypofluorite; CC12CF2, thermal reaction with CF3OF; CF3OF, thermal reaction with CC12CF2; Perfluorobutene-2; Trifluoromethylhypofluorite, addition to 1,1-dichlorodifluoroethylene |
| Año: | 1988 |
| Volumen: | 158 |
| Número: | Part_1 |
| Página de inicio: | 25 |
| Página de fin: | 34 |
| DOI: | http://dx.doi.org/10.1524/zpch.1988.158.Part_1.025 |
| Título revista: | Zeitschrift fur Physikalische Chemie |
| Título revista abreviado: | Z. Phys. Chem. |
| ISSN: | 09429352 |
| Registro: | https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_09429352_v158_nPart_1_p25_DosSantosAfonso |
Referencias:
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Citas:
---------- APA ----------
Dos Santos Afonso, M. & Czarnowski, J. (1988) . Kinetics and Mechanism of the Thermal Reaction between Trifluoromethylhypofluorite and 1,1-Dichlorodifluoroethylene. Zeitschrift fur Physikalische Chemie, 158(Part_1), 25-34.http://dx.doi.org/10.1524/zpch.1988.158.Part_1.025
---------- CHICAGO ----------
Dos Santos Afonso, M., Czarnowski, J. "Kinetics and Mechanism of the Thermal Reaction between Trifluoromethylhypofluorite and 1,1-Dichlorodifluoroethylene" . Zeitschrift fur Physikalische Chemie 158, no. Part_1 (1988) : 25-34.http://dx.doi.org/10.1524/zpch.1988.158.Part_1.025
---------- MLA ----------
Dos Santos Afonso, M., Czarnowski, J. "Kinetics and Mechanism of the Thermal Reaction between Trifluoromethylhypofluorite and 1,1-Dichlorodifluoroethylene" . Zeitschrift fur Physikalische Chemie, vol. 158, no. Part_1, 1988, pp. 25-34.http://dx.doi.org/10.1524/zpch.1988.158.Part_1.025
---------- VANCOUVER ----------
Dos Santos Afonso, M., Czarnowski, J. Kinetics and Mechanism of the Thermal Reaction between Trifluoromethylhypofluorite and 1,1-Dichlorodifluoroethylene. Z. Phys. Chem. 1988;158(Part_1):25-34.http://dx.doi.org/10.1524/zpch.1988.158.Part_1.025
