Artículo
Destsillats, H.; Fernandez-Prini, R. "Solubility of i2 and formation of f2-arene charge-transfer complexes in supercritical SF6" (1998) Journal of the Chemical Society - Faraday Transactions. 94(7):871-878
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Abstract:
The solubility of I2(s) has been measured spectrophotometrically in supercritical SF6 with and without the addition of benzene and mesitylene at temperatures, T = 323.95. 330.00 and 340.55 K over the pressure range 2-10 MPa. It was possible to obtain the solubility of iodine and the concentration of the charge-transfer complex from the visible and UV bands of the spectra over The fluid density range 1.0-9.1 mol dm-3. The results support the view that interactions between iodine and the arene molecules are restricted to Leonard-Jones plus multipcle interactions. The observed variation with fluid density of the equilibrium concentration quotient for charge-transfer complex formation may be correlated with the density dependence of the excess number of I2-arene collisions. No evidence for the existence of critical clustering has been found.
Registro:
| Documento: | Artículo |
| Título: | Solubility of i2 and formation of f2-arene charge-transfer complexes in supercritical SF6 |
| Autor: | Destsillats, H.; Fernandez-Prini, R. |
| Filiación: | Institute de Quimica Fisica de Materielles, Ambiente y Energia, Facuhad de Ciencias Exactas y Naturales, Ciudad Universitaria Pabellón II, 1428-Capital Federal, Argentina Unidad de Actividad Quimica, Comision National de Energia Atómica, Av. Libertador 8250, 1429-Capital Federal, Argentina |
| Año: | 1998 |
| Volumen: | 94 |
| Número: | 7 |
| Página de inicio: | 871 |
| Página de fin: | 878 |
| Título revista: | Journal of the Chemical Society - Faraday Transactions |
| ISSN: | 09565000 |
| Registro: | https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_09565000_v94_n7_p871_Destsillats |
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Citas:
---------- APA ----------
Destsillats, H. & Fernandez-Prini, R. (1998) . Solubility of i2 and formation of f2-arene charge-transfer complexes in supercritical SF6. Journal of the Chemical Society - Faraday Transactions, 94(7), 871-878.Recuperado de https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_09565000_v94_n7_p871_Destsillats [ ]
---------- CHICAGO ----------
Destsillats, H., Fernandez-Prini, R. "Solubility of i2 and formation of f2-arene charge-transfer complexes in supercritical SF6" . Journal of the Chemical Society - Faraday Transactions 94, no. 7 (1998) : 871-878.Recuperado de https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_09565000_v94_n7_p871_Destsillats [ ]
---------- MLA ----------
Destsillats, H., Fernandez-Prini, R. "Solubility of i2 and formation of f2-arene charge-transfer complexes in supercritical SF6" . Journal of the Chemical Society - Faraday Transactions, vol. 94, no. 7, 1998, pp. 871-878.Recuperado de https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_09565000_v94_n7_p871_Destsillats [ ]
---------- VANCOUVER ----------
Destsillats, H., Fernandez-Prini, R. Solubility of i2 and formation of f2-arene charge-transfer complexes in supercritical SF6. 1998;94(7):871-878.Available from: https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_09565000_v94_n7_p871_Destsillats [ ]
