Artículo

Petroselli, G.; Mandal, M.K.; Chen, L.C.; Hiraoka, K.; Nonami, H.; Erra-Balsells, R. "In situ analysis of soybeans and nuts by probe electrospray ionization mass spectrometry" (2015) Journal of Mass Spectrometry. 50(4):676-682
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Abstract:

The probe electrospray ionization (PESI) is an ESI-based ionization technique that generates electrospray from the tip of a solid metal needle. In the present work, we describe the PESI mass spectra obtained by in situ measurement of soybeans and several nuts (peanuts, walnuts, cashew nuts, macadamia nuts and almonds) using different solid needles as sampling probes. It was found that PESI-MS is a valuable approach for in situ lipid analysis of these seeds. The phospholipid and triacylglycerol PESI spectra of different nuts and soybean were compared by principal component analysis (PCA). PCA shows significant differences among the data of each family of seeds. Methanolic extracts of nuts and soybean were exposed to air and sunlight for several days. PESI mass spectra were recorded before and after the treatment. Along the aging of the oil (rancidification), the formation of oxidated species with variable number of hydroperoxide groups could be observed in the PESI spectra. The relative intensity of oxidated triacylglycerols signals increased with days of exposition. Monitoring sensitivity of PESI-MS was high. This method provides a fast, simple and sensitive technique for the analysis (detection and characterization) of lipids in seed tissue and degree of oxidation of the oil samples. Copyright © 2015 John Wiley & Sons, Ltd. Copyright © 2015 John Wiley & Sons, Ltd.

Registro:

Documento: Artículo
Título:In situ analysis of soybeans and nuts by probe electrospray ionization mass spectrometry
Autor:Petroselli, G.; Mandal, M.K.; Chen, L.C.; Hiraoka, K.; Nonami, H.; Erra-Balsells, R.
Filiación:Departamento de Química Orgánica, Facultad de Ciencias Exactas, Naturales, Universidad de Buenos Aires, Pabellõn II 3 P, Buenos Aires, 1428, Argentina
Clean Energy Research Center, University of Yamanashi, 4-3-11 Takeda, Kofu, Yamanashi, 400-8511, Japan
Plant Biophysics/Biochemistry Research Laboratory, Faculty of Agriculture, Ehime University, Matsuyama, 790-8566, Japan
Palabras clave:almonds; cashew nuts; ESI-MS; macadamia nuts; peanuts; PESI; pistachios; rancidification; walnuts; Electrospray ionization; Glycerol; Ionization; Mass spectrometers; Mass spectrometry; Needles; Phospholipids; Probes; almonds; Cashew nut; ESI-MS; Macadamia nuts; peanuts; PESI; pistachios; rancidification; walnuts; Principal component analysis; hydroperoxide; methanol; phospholipid; triacylglycerol; phospholipid; triacylglycerol; acidification; aging; air; almond; Article; cashew nut; comparative study; electrospray mass spectrometry; lipid analysis; lipid composition; Macadamia; molecular probe; molecular weight; nut; oxidation; peanut; principal component analysis; priority journal; probe electrospray ionization mass spectrometry; rancidification; soybean; sunlight; walnut; Arachis; chemistry; devices; electrospray mass spectrometry; nut; procedures; soybean; Anacardium occidentale; Glycine max; Juglans; Macadamia; Arachis; Juglans; Macadamia; Nuts; Phospholipids; Principal Component Analysis; Soybeans; Spectrometry, Mass, Electrospray Ionization; Triglycerides
Año:2015
Volumen:50
Número:4
Página de inicio:676
Página de fin:682
DOI: http://dx.doi.org/10.1002/jms.3575
Título revista:Journal of Mass Spectrometry
Título revista abreviado:J. Mass Spectrom.
ISSN:10765174
CODEN:JMSPF
CAS:methanol, 67-56-1; Phospholipids; Triglycerides
Registro:https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_10765174_v50_n4_p676_Petroselli

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Citas:

---------- APA ----------
Petroselli, G., Mandal, M.K., Chen, L.C., Hiraoka, K., Nonami, H. & Erra-Balsells, R. (2015) . In situ analysis of soybeans and nuts by probe electrospray ionization mass spectrometry. Journal of Mass Spectrometry, 50(4), 676-682.
http://dx.doi.org/10.1002/jms.3575
---------- CHICAGO ----------
Petroselli, G., Mandal, M.K., Chen, L.C., Hiraoka, K., Nonami, H., Erra-Balsells, R. "In situ analysis of soybeans and nuts by probe electrospray ionization mass spectrometry" . Journal of Mass Spectrometry 50, no. 4 (2015) : 676-682.
http://dx.doi.org/10.1002/jms.3575
---------- MLA ----------
Petroselli, G., Mandal, M.K., Chen, L.C., Hiraoka, K., Nonami, H., Erra-Balsells, R. "In situ analysis of soybeans and nuts by probe electrospray ionization mass spectrometry" . Journal of Mass Spectrometry, vol. 50, no. 4, 2015, pp. 676-682.
http://dx.doi.org/10.1002/jms.3575
---------- VANCOUVER ----------
Petroselli, G., Mandal, M.K., Chen, L.C., Hiraoka, K., Nonami, H., Erra-Balsells, R. In situ analysis of soybeans and nuts by probe electrospray ionization mass spectrometry. J. Mass Spectrom. 2015;50(4):676-682.
http://dx.doi.org/10.1002/jms.3575