Abstract:
A record Co36 cluster is prepared. This mixed-valent compound containing CoII and CoIII centers is formed in the reaction of a dinuclear cobalt pivalate species with the polydentate 2,3-dicarboxypyrazine ligand. In terms of magnetic properties it behaves as a {Co16-Co16} supramolecular dimer in which the S = A spin ground states of each monomer do not interact. "chemical equation presented" © 2009 Wiley-VCH Verlag GmbH & Co. KGaA,.
Registro:
Documento: |
Artículo
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Título: | A Co36 cluster assembled from the reaction of cobalt pivalate with 2,3-dicarboxypyrazine |
Autor: | Alborés, P.; Rentschler, E. |
Filiación: | Departamento de Química Inorgánica, Analítica y Química Física-INQUIMAE (CONICET), Universidad de Buenos Aires, Buenos Aires, Argentina Institut für Anorganische und Analytische Chemie, Johannes-Gutenberg-Universität, 55099 Mainz, Germany
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Palabras clave: | Cluster compounds; Cobalt; Dicarboxypyrazine; Magnetic properties; Chemical equations; Cluster compounds; Dinuclear; Mixed-valent compounds; Spin ground state; Chemical reactions; Cobalt; Magnetic properties; Cobalt compounds |
Año: | 2009
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Volumen: | 48
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Número: | 49
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Página de inicio: | 9366
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Página de fin: | 9370
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DOI: |
http://dx.doi.org/10.1002/anie.200904743 |
Título revista: | Angewandte Chemie - International Edition
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Título revista abreviado: | Angew. Chem. Int. Ed.
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ISSN: | 14337851
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CODEN: | ACIEA
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Registro: | https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_14337851_v48_n49_p9366_Albores |
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Citas:
---------- APA ----------
Alborés, P. & Rentschler, E.
(2009)
. A Co36 cluster assembled from the reaction of cobalt pivalate with 2,3-dicarboxypyrazine. Angewandte Chemie - International Edition, 48(49), 9366-9370.
http://dx.doi.org/10.1002/anie.200904743---------- CHICAGO ----------
Alborés, P., Rentschler, E.
"A Co36 cluster assembled from the reaction of cobalt pivalate with 2,3-dicarboxypyrazine"
. Angewandte Chemie - International Edition 48, no. 49
(2009) : 9366-9370.
http://dx.doi.org/10.1002/anie.200904743---------- MLA ----------
Alborés, P., Rentschler, E.
"A Co36 cluster assembled from the reaction of cobalt pivalate with 2,3-dicarboxypyrazine"
. Angewandte Chemie - International Edition, vol. 48, no. 49, 2009, pp. 9366-9370.
http://dx.doi.org/10.1002/anie.200904743---------- VANCOUVER ----------
Alborés, P., Rentschler, E. A Co36 cluster assembled from the reaction of cobalt pivalate with 2,3-dicarboxypyrazine. Angew. Chem. Int. Ed. 2009;48(49):9366-9370.
http://dx.doi.org/10.1002/anie.200904743