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Abstract:

The insertion of a metal atom in the central cavity of adsorbed porphyrins is an important subject as it allows specific control over the functionality of the molecule. In this work, metalation of protoporphyrin IX (PPIX) molecules bonded directly to a Au(111) surface or to a self-assembled monolayer (SAM) on Au(111) was studied at the solid-liquid interface. X-ray photoelectron spectroscopy (XPS) and scannning tunneling microscopy demonstrate that the molecules bind to the SAM without forming aggregates and with a surface coverage below the monolayer. Nearedge X-ray absorption fine structure spectroscopy and surface-enhanced resonance Raman spectroscopy demonstrate that the molecules are bonded to the SAM with a tilted molecular plane. XPS measurements show that PPIX molecules bonded to the SAM and exposed to Zn2+ containing aqueous solutions are metalated to a small extent at room temperature and fully metalated at 350 K. In contrast, PPIX molecules adsorbed directly to the Au(111) surface are fully metalated at room temperature. These results show that surface-molecule interactions could have an impact on the metalation of porphyrin molecules. © 2017 American Chemical Society.

Registro:

Documento: Artículo
Título:Surface influence on the metalation of porphyrins at the solid-liquid interface
Autor:Fernandez, C.C.; Spedalieri, C.; Murgida, D.H.; Williams, F.J.
Filiación:Departamento de Química Inorganica, Analítica y Química Física, Facultad de Ciencias Exactas y Naturales, INQUIMAE-CONICET, Universidad de Buenos Aires, Ciudad Universitaria, Pabellon 2, Buenos Aires, C1428EHA, Argentina
Palabras clave:Chemical reactions; Metals; Molecules; Monolayers; Phase interfaces; Porphyrins; Self assembled monolayers; Solutions; X ray absorption; X ray absorption fine structure spectroscopy; Porphyrin molecules; Protoporphyrin IX; Scannning tunneling microscopies; Solid-liquid interfaces; Surface coverages; Surface influences; Surface molecules; Surface-enhanced resonance raman spectroscopies; X ray photoelectron spectroscopy
Año:2017
Volumen:121
Número:39
Página de inicio:21324
Página de fin:21332
DOI: http://dx.doi.org/10.1021/acs.jpcc.7b04983
Título revista:Journal of Physical Chemistry C
Título revista abreviado:J. Phys. Chem. C
ISSN:19327447
Registro:https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_19327447_v121_n39_p21324_Fernandez

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Citas:

---------- APA ----------
Fernandez, C.C., Spedalieri, C., Murgida, D.H. & Williams, F.J. (2017) . Surface influence on the metalation of porphyrins at the solid-liquid interface. Journal of Physical Chemistry C, 121(39), 21324-21332.
http://dx.doi.org/10.1021/acs.jpcc.7b04983
---------- CHICAGO ----------
Fernandez, C.C., Spedalieri, C., Murgida, D.H., Williams, F.J. "Surface influence on the metalation of porphyrins at the solid-liquid interface" . Journal of Physical Chemistry C 121, no. 39 (2017) : 21324-21332.
http://dx.doi.org/10.1021/acs.jpcc.7b04983
---------- MLA ----------
Fernandez, C.C., Spedalieri, C., Murgida, D.H., Williams, F.J. "Surface influence on the metalation of porphyrins at the solid-liquid interface" . Journal of Physical Chemistry C, vol. 121, no. 39, 2017, pp. 21324-21332.
http://dx.doi.org/10.1021/acs.jpcc.7b04983
---------- VANCOUVER ----------
Fernandez, C.C., Spedalieri, C., Murgida, D.H., Williams, F.J. Surface influence on the metalation of porphyrins at the solid-liquid interface. J. Phys. Chem. C. 2017;121(39):21324-21332.
http://dx.doi.org/10.1021/acs.jpcc.7b04983